纳米复合磁体的磁能积能得到大幅度提高,前提是晶粒之间存在良好的交换耦合作用,而交换耦合作用与软、硬磁相之间的界面密切相关.对Nd2Fe14B、Sm-Co、FePt基纳米复合磁体界面交换耦合和反磁化的研究展开论述.在不同的条件下,界面结构的匹配性、界面原子扩散、晶间的非晶相、界面非磁性层、界面晶格弛豫等可能有利于改善界面的结构、增强交换耦合作用,进而对反磁化过程产生影响.反磁化的不可逆过程主要发生在硬磁相内,但与软、硬磁相界面特性密切相关.不可逆反磁化在一定程度上决定了磁体的矫顽力,它可通过改善界面结构进行调控.本文旨在对纳米复合磁体界面的作用深入理解并期望能对磁体磁性能的优化提供参考.
参考文献
[1] | 靳朝相;曾燮榕;盛洪超.磷对钕铁硼纳米复合永磁材料晶粒取向和尺寸的影响[J].功能材料,2013(15):2232-2234,2238. |
[2] | NICOLA JONES.THE PULL OF STRONGER MAGNETS[J].Nature,2011Apr.7 TN.7341(Apr.7 TN.7341):22-23. |
[3] | 韩广兵;苏浩;余丽莉;朱明刚;李卫.纳米复合永磁材料中软硬磁性相间交换耦合作用的表征[J].功能材料,2013(20):2990-2995. |
[4] | 杨丽萍;谭晓华;徐晖;徐兴国.纳米晶复合Nd_(9.5)Fe_(76)Co_5Zr_(3-x)Nb_xB_(6.5)(x=0~3.0)粘结磁体的磁性能和温度系数的研究[J].功能材料,2012(9):1102-1105. |
[5] | Z. B. Li;M. Zhang;B. G. Shen;J. R. Sun.Non-uniform magnetization reversal in nanocomposite magnets[J].Applied physics letters,201310(10):102405-1-102405-4. |
[6] | Kneller E.F.;Hawig R..The exchange-spring magnet: a new material principle for permanent magnets[J].IEEE Transactions on Magnetics,19914(4):3588-3560. |
[7] | Wang, Y.;Huang, Y.;Wang, Q..Preparation and magnetic properties of BaFe _(12)O _(19)/Ni _(0.8)Zn _(0.2)Fe _2O _4 nanocomposite ferrite[J].Journal of Magnetism and Magnetic Materials,201219(19):3024-3028. |
[8] | A. Lopez-Ortega;M. Estrada;G. Salazar-Alvarez.Strongly exchange coupled inverse ferrimagnetic soft/hard, Mn_xFe_(3-x)O4/Fe_xMn_(3-x)O4, core/shell heterosrructured nanoparticles[J].Nanoscale,201216(16):5138-5147. |
[9] | Fischer R.;Kronmuller H..Importance of ideal grain boundaries of high remanent composite permanent magnets[J].Journal of Applied Physics,19986(6):3271-3275. |
[10] | Kim, EC;Kim, SJ;Baek, JK;Lee, SR.Mossbauer study of intergranular phase in Nd8Fe86-xNbxB6(x=0, 1, 2, 3) nanocomposite magnet[J].Hyperfine Interactions,20081/3(1/3):55-60. |
[11] | Yongmei Zhang;Wei Li;Hailing Li;Xiangyi Zhang.Coercivity mechanism of α-Fe/Nd_2Fe_(14)B nanocomposite magnets with an intergranular amorphous phase[J].Journal of Physics, D. Applied Physics: A Europhysics Journal,20141(1):015002-1-015002-7. |
[12] | Li SD.;Gu BX.;Bi H.;Tian ZJ.;Xie GZ.;Zhu YJ.;Du YW..Role of amorphous grain boundaries in nanocomposite NdFeB permanent magnets[J].Journal of Applied Physics,200212(12):7514-7518. |
[13] | Duc-The Ngo;Hong-Gam Duong;Hoang-Hai Nguyen;Chau Nguyen;Mohammed Basith;Duc-Quang Hoang.The microstructure, high performance magnetic hardness and magnetic after-effect of an α -FeCo/Pr_2Fe_(14)B nanocomposite magnet with low Pr concentration[J].Nanotechnology,200916(16):165707-6. |
[14] | Zhang XY.;Guan Y.;Zhang JW..Study of interface structure of alpha-Fe/Nd2Fe14B nanocomposite magnets[J].Applied physics letters,200211(11):1966-1968. |
[15] | 计齐根;田宗军;顾本喜;章建荣;都有为.Nd2Fe14B/α-Fe/非晶Nd-Fe-B三相纳米交换耦合磁体中的结构弛豫[J].金属学报,2001(5):463-466. |
[16] | F. Yang;W. Liu;W. B. Cui;J. N. Feng;Z. D. Zhang.Magnetic Properties of Anisotropic Pr-Fe-B/Fe/Pr-Fe-B Films[J].Journal of Superconductivity and Novel Magnetism,20126(6):2059-2062. |
[17] | Liu Wei;Liu Xiong-Hua;Cui Wei-Bin;Gong Wen-Jie;Zhang Zhi-Dong.Exchange couplings in magnetic films[J].中国物理B(英文版),2013(2):1-22. |
[18] | Cui, W. B.;Sepehri-Amin, H.;Takahashi, Y. K.;Hono, K..Hard magnetic properties of spacer-layer-tuned NdFeB/Ta/Fe nanocomposite films[J].Acta materialia,2015:405-412. |
[19] | Wei-Bin Cui;Yukiko K. Takahashi;Kazuhiro Hono.Nd_2Fe_14B/FeCo Anisotropic Nanocomposite Films with a Large Maximum Energy Product[J].Advanced Materials,201248(48):6530-6535. |
[20] | Rong, C.B.;Wang, D.;Nguyen, V.V.;Daniil, M.;Willard, M.A.;Zhang, Y.;Kramer, M.J.;Liu, J.P..Effect of selective Co addition on magnetic properties of Nd_2(FeCo)_(14)B/α-Fe nanocomposite magnets[J].Journal of Physics, D. Applied Physics: A Europhysics Journal,20134(4):045001-1-045001-5. |
[21] | J. Zhang;Y. K. Takahashi;R. Gopalan;K. Hono.Sm(Co,Cu)_5/Fe exchange spring multilayer films with high energy product[J].Applied physics letters,200512(12):122509.1-122509.3. |
[22] | Furrukh Shahzad;Saadat Anwar -Siddiqi;Shi-Shen Yan;Xu Jing;Bail-long-hang;Tang Min-jian;Xing Peng-fei;He Shu-min;Tong-shuai.Effect of Mo interlayer on magnetic properties of exchange coupled Sm-Co/Fe bilayers[J].Brazilian journal of physics,20102(2):201-203. |
[23] | Le Breton, JM;Larde, R;Chiron, H;Pop, V;Givord, D;Isnard, O;Chicinas, I.A structural investigation of SmCo5/Fe nanostructured alloys obtained by high-energy ball milling and subsequent annealing[J].Journal of Physics, D. Applied Physics: A Europhysics Journal,20108(8):085001:1-085001:8. |
[24] | Xiong, X.Y.;Rong, C.B.;Rubanov, S.;Zhang, Y.;Liu, J.P..Atom probe study on the bulk nanocomposite SmCo/Fe permanent magnet produced by ball-milling and warm compaction[J].Journal of Magnetism and Magnetic Materials,201122(22):2855-2858. |
[25] | Saravanan, P.;Hsu, J.-H.;Gayen, A.;Singh, A.K.;Perumal, A.;Reddy, G.L.N.;Kumar, S.;Kamat, S.V..Effect of Fe layer thickness and Fe/Co intermixing on the magnetic properties of Sm-Co/Fe bilayer exchange-spring magnets[J].Journal of Physics, D. Applied Physics: A Europhysics Journal,201315(15):155002-1-155002-7. |
[26] | Rodrigue Larde;Jean-Marie Le Breton;Adeline Maitre.Atomic-Scale Investigation of SmCo5/α-Fe Nanocomposites: influence of Fe/Co interdiffusion on the Magnetic Properties[J].The journal of physical chemistry, C. Nanomaterials and interfaces,201315(15):7801-7810. |
[27] | Liu, X.B.;Altounian, Z..Magnetic moments and exchange interaction in Sm(Co, Fe)_5 from first-principles[J].Computational Materials Science,20113(3):841-846. |
[28] | Ying Zhang;M. J. Kramer;Chuanbing Rong;J. Ping Liu.Microstructure and intergranular diffusion in exchange-coupled Sm-Co/Fe nanocomposites[J].Applied physics letters,20103(3):032506-1-032506-3. |
[29] | Yaohua Liu;S. G. E. te Velthuis;J. S. Jiang;Y. Choi;S. D. Bader;A. A. Parizzi;H. Ambaye;V. Lauter.Magnetic structure in Fe/Sm-Co exchange spring bilayers with intermixed interfaces[J].Physical review, B. Condensed matter and materials physics,201117(17):174418:1-174418:7. |
[30] | Choi Y;Jiang JS;Ding Y;Rosenberg RA;Pearson JE;Bader SD;Zambano A;Murakami M;Takeuchi I;Wang ZL.Role of diffused Co atoms in improving effective exchange coupling in Sm-Co/Fe spring magnets[J].Physical review, B. Condensed matter and materials physics,200710(10):4432-1-4432-6-0. |
[31] | Jiang JS;Pearson JE;Liu ZY;Kabius B;Trasobares S;Miller DJ;Bader SD;Lee DR;Haskel D;Srajer G.Improving exchange-spring nanocomposite permanent magnets[J].Applied physics letters,200422(22):5293-5295. |
[32] | Ying Zhang;M. J. Kramer;Debjani Banerjee;Ichiro Takeuchi;J. Ping Liu.Transmission electron microscopy study on Co/Fe interdiffusion in SmCo_(5)/Fe and Sm_(2)Co_(7)/Fe/Sm_(2)Co_(7) thin films[J].Journal of Applied Physics,20115(5):053914-1-053914-4. |
[33] | Yuzi Liu;Y. Q. Wu;M. J. Kramer;Y. Choi;J. S. Jiang;Z. L. Wang;J. P. Liu.Microstructure analysis of a SmCo/Fe exchange spring bilayer[J].Applied physics letters,200819(19):192502-1-192502-3-0. |
[34] | Yu MH;Hattrick-Simpers J;Takeuchi I;Li J;Wang ZL;Liu JP;Lofland SE;Tyagi S;Freeland JW;Giubertoni D.Interphase exchange coupling in Fe/Sm-Co bilayers with gradient Fe thickness[J].Journal of Applied Physics,20056(6):3908-1-3908-4-0. |
[35] | F. Casoli;F. Albertini;L. Nasi.Role of interface morphology in the exchange-spring behavior of FePt/Fe perpendicular bilayers[J].Acta materialia,201010(10):3594-3601. |
[36] | F. Casoli;F. Albertini;L. Nasi;S. Fabbrici;R. Cabassi;F. Bolzoni;C. Bocchi.Strong coercivity reduction in perpendicular FePt/Fe bilayers due to hard/soft coupling[J].Applied physics letters,200814(14):142506-1-142506-3-0. |
[37] | Gayen, A.;Biswas, B.;Singh, A.K.;Saravanan, P.;Perumal, A..High temperature magnetic properties of indirect exchange spring FePt/M(Cu,C)/Fe trilayer thin films[J].Journal of nanomaterials,2013Pt.4(Pt.4):718365-1-718365-9. |
[38] | C. J. Aas;P. J. Hasnip;R. Cuadrado;E. M. Plotnikova;L. Szunyogh;L. Udvardi;R. W. Chantrell.Exchange coupling and magnetic anisotropy at Fe/FePt interfaces[J].Physical review, B. Condensed matter and materials physics,201317(17):174409-1-174409-11. |
[39] | Interface structures in FePt/Fe_(3)Pt hard-soft exchange-coupled magnetic nanocomposites[J].Applied physics letters,200321(21):3743-3745. |
[40] | Bauer J.;Zern A.;Kronmuller H.;Seeger M..NANOCRYSTALLINE FENDB PERMANENT MAGNETS WITH ENHANCED REMANENCE[J].Journal of Applied Physics,19963(3):1667-1673. |
[41] | Z. B. Li;B. G. Shen;E. Niu;J. R. Sun.Nucleation of reversed domain and pinning effect on domain wall motion in nanocomposite magnets[J].Applied physics letters,20136(6):062405-1-062405-4. |
[42] | 李柱柏;刘新才;潘晶;张辉;张文旺.Nd-Fe-B基纳米复合永磁材料矫顽力及其机制的研究进展[J].稀有金属材料与工程,2010(10):1868-1874. |
[43] | G. P. Zhao;M. G. Zhao;H. S. Lim;Y. P. Feng;C. K. Ong.From nucleation to coercivity[J].Applied physics letters,200516(16):162513-1-162513-3-0. |
[44] | Russier, V.;Younsi, K.;Bessais, L..Nanostructured exchange coupled hard/soft composites: From the local magnetization profile to an extended 3d simple model[J].Journal of Magnetism and Magnetic Materials,20126(6):1122-1128. |
[45] | Zhao GP;Wang XL;Yang C;Xie LH;Zhou G.Self-pinning: Dominant coercivity mechanism in exchange-coupled permanent/composite magnets[J].Journal of Applied Physics,20079 Pt.2(9 Pt.2):K9102-1-K9102-3-0. |
[46] | Li, Z. B.;Shen, B. G.;Zhang, M.;Zhang, Y.;Hu, F. X.;Sun, J. R..Irreversible magnetization and self-interaction investigated by thermal activation in Pr2Fe14B magnets[J].Applied physics letters,20154(4):042403-1-042403-4. |
[47] | Hellwig O.;Takano K.;Fullerton EE.;Kortright JB..Switching behavior of Fe-Pt/Ni-Fe exchange-spring films studied by resonant soft-x-ray magneto-optical Kerr effect[J].Physical Review.B.Condensed Matter,200017(17):11694-11698. |
[48] | Choi Y;Jiang JS;Pearson JE;Bader SD;Liu JP.Origin of recoil hysteresis loops in Sm-Co/Fe exchange-spring magnets[J].Applied physics letters,20072(2):22502-1-22502-3-0. |
[49] | Z. B. Li;B. G. Shen;J. R. Sun.Origin of recoil hysteresis in nanocomposite Pr_8Fe_(87)B_5 magnets[J].Journal of Applied Physics,20131(1):013902-1-013902-4. |
[50] | Z. B. Li;M. Zhang;L. C. Wang;B. G. Shen;X. F. Zhang;Y. F. Li;F. X. Hu;J. R. Sun.Investigation on intergranular exchange coupling effect in Pr_9Fe_(85.5)B_(5.5) ribbons[J].Applied physics letters,20145(5):052406-1-052406-4. |
[51] | Loxley PN;Stamps RL.Theory for nucleation at an interface and magnetization reversal of a two-layer nanowire[J].Physical review, B. Condensed matter and materials physics,20062(2):4420-1-4420-14-0. |
[52] | Y. Choi;J. S. Jiang;J. E. Pearson;S. D. Bader;J. J. Kavich;J. W. Freeland;J. P. Liu.Controlled interface profile in Sm-Co/Fe exchange-spring magnets[J].Applied physics letters,20077(7):072509-1-072509-3-0. |
[53] | Fang Wang;Xiaohong Xu;Yan Liang;Jing Zhang;Haishun Wu.FeAu/FePt exchange-spring media fabricated by magnetron sputtering and postannealing[J].Applied Physics Letters,20092(2):022516-1--022516-3-0. |
[54] | Hailing Li;Li Lou;Fuchen Hou;Defeng Guo;Wei Li;Xiaohong Li;Dmitry V. Gunderov;Kiminori Sato;Xiangyi Zhang.Simultaneously increasing the magnetization and coercivity of bulk nanocomposite magnets via severe plastic deformation[J].Applied physics letters,201314(14):142406-1-142406-5. |
上一张
下一张
上一张
下一张
计量
- 下载量()
- 访问量()
文章评分
- 您的评分:
-
10%
-
20%
-
30%
-
40%
-
50%