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以氨气作为氮源,硫脲作为硫源,制备N/S共掺杂SrSnO3样品.通过X射线粉末衍射仪(XRD)和X射线光电子能谱(XPS)表征确定了N、S分别是以晶格取代和间隙掺杂的形式存在于样品中.紫外漫反射光谱(DRS)表明氮硫共掺杂的样品对可见光的吸收比单掺杂要强.以罗丹明B、亚甲基蓝、橙黄Ⅱ号作为模拟废水污染物并考察了样品在可见光下降解染料的活性.实验结果表明,在氮化时间为12h,硫掺杂比为1∶1得到的N/S共掺杂SrSnO3的催化剂在可见光照射的条件下,一定浓度的罗丹明B溶液在6h内被彻底降解至无色溶液,亚甲基蓝溶液的在3h内,脱色率达到96%以上,偶氮类染料橙黄Ⅱ号在加入少量H2O2,3.5h内降解率为93%.

参考文献

[1] 王绍温;陈胜;孙德智.物化法处理印染废水的研究进展[J].工业水处理,2010(1):8-12.
[2] 朱百鸣;江元;彭绍琴;李越湘.环境条件对氟、氮共掺杂TiO2光催化降解甲醛活性的影响[J].有色金属(冶炼部分),2011(4):44-46.
[3] Chen DM;Jiang ZY;Geng JQ;Wang Q;Yang D.Carbon and nitrogen co-doped TiO2 with enhanced visible-light photocatalytic activity[J].Industrial & Engineering Chemistry Research,20079(9):2741-2746.
[4] 李辉;王金淑;李洪义;YIN Shu;SATO Tsugio.氮硫掺杂介孔TiO2 薄膜结构及其光催化性能[J].无机材料学报,2009(5):909-914.
[5] Dong F;Zhao WR;Wu ZB.Characterization and photocatalytic activities of C, N and S co-doped TiO2 with 1D nanostructure prepared by the nano-confinement effect[J].Nanotechnology,200836(36):365607-1-365607-10-0.
[6] Di Chen;Jinhua Ye.SrSnO3 Nanostructures:Synthesis,Characterization,and Photocatalytic Properties[J].Chemistry of Materials: A Publication of the American Chemistry Society,200718(18):4585-4591.
[7] Enhanced Visible Light Photocatalytic Activity Of Zn_2sno_4 Via Sulfur Anion-doping[J].Materials Letters,200913/14(13/14):1169-1171.
[8] Ji Young Kim;Chan Soo Kim;Han Kwon Chang.Synthesis and characterization of N-doped TiO2/ZrO2 visible light photocatalysts[J].Advanced Powder Technology: The internation Journal of the Society of Powder Technology, Japan,20113(3):443-448.
[9] T. Umebayashi;T. Yamaki;H. Itoh;K. Asai.Band gap narrowing of titanium dioxide by sulfur doping[J].Applied physics letters,20023(3):454-456.
[10] Ohno, T;Tsubota, T;Toyofuku, M;Inaba, R.Photocatalytic activity of a TiO2 photocatalyst doped with C4+ and S4+ ions having a rutile phase under visible light[J].Catalysis Letters,20044(4):255-258.
[11] ZrW_2O_8 photocatalyst and its visible-light sensitization via sulfur anion doping for water splitting[J].International journal of hydrogen energy,201013(13):7043-7050.
[12] Hiroshi Irie;Yuka Watanabe;Kazuhito Hashimoto.Nitrogen-Concentration Dependence on Photocatalytic Activity of TiO_(2-x)N_x Powders[J].The journal of physical chemistry, B. Condensed matter, materials, surfaces, interfaces & biophysical,200323(23):5483-5486.
[13] Rahima A. Lucky;Paul A. Charpentier.N-doped ZrO2/TiO2 bimetallic materials synthesized in supercritical CO2: Morphology and photocatalytic activity[J].Applied Catalysis, B. Environmental: An International Journal Devoted to Catalytic Science and Its Applications,20103/4(3/4):516-523.
[14] C.Hu;Jimmy C.Yu;Z.Hao;P.K.Wong.Effects of acidity and inorganic ions on the photocatalytic degradation of different azo dyes[J].Applied Catalysis, B. Environmental: An International Journal Devoted to Catalytic Science and Its Applications,20031(1):35-47.
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