以钛酸四丁酯为前驱物,无水乙醇为溶剂,聚乙二醇200为分散剂,三乙醇胺为抑制剂,采用溶胶-凝胶法制备了锐钛矿型硫镧共掺杂纳米TiO2(S-La-TiO2),通过透射电镜(TEM)、X射线衍射(XRD)、紫外-可见光谱(UV-Vis)等对材料的结构形貌进行了表征分析.并以甲醛作为目标污染物,研究了材料在不同光源照射条件下对甲醛的催化降解性能与机理.实验结果表明,S与La共掺杂提高了纳米TiO2在紫外光和可见光照射下的光催化活性,所制备的S-La-TiO2是一种性能良好的甲醛降解材料.在La的含量一定时,随S含量增加,材料对甲醛的降解率先增大后减小,当样品中各元素物质的量之比n(S):n(La):n(Ti)为1:0.01:1时的降解效果最好.
参考文献
[1] | Catherine M. Schmidt;Avram M. Buchbinder;Eric Weitz.Photochemistry of the Indoor Air Pollutant Acetone on Degussa P25 TiO2 Studied by Chemical Ionization Mass Spectrometry[J].The journal of physical chemistry, A. Molecules, spectroscopy, kinetics, environment, & general theory,200750(50):13023-13031. |
[2] | 宋金玲;周长才;牟连维;郭冠铭;蔡颖;张胤.溶胶-凝胶法制备掺杂稀土元素二氧化钛及其气敏性能[J].过程工程学报,2013(1):170-174. |
[3] | Destaillats H;Lunden MM;Singer BC;Coleman BK;Hodgson AT;Weschler CJ;Nazaroff WW.Indoor secondary pollutants from household product emissions in the presence of ozone: A bench-scale chamber study[J].Environmental Science & Technology: ES&T,200614(14):4421-4428. |
[4] | M. J. Mendell.Indoor residential chemical emissions as risk factors for respiratory and allergic effects in children: a review[J].Indoor air,20074(4):259-277. |
[5] | Peng Zhou;Xiaofeng Zhu;Jiaguo Yu.Effects of Adsorbed F, OH, and CI Ions on Formaldehyde Adsorption Performance and Mechanism of Anatase TiO2 Nanosheets with Exposed {001} Facets[J].ACS applied materials & interfaces,201316(16):8165-8172. |
[6] | YAO Yadong;GUO Xiangli;KANG Yunqing;LI Xieji;CHEN Aizheng;YANG Weizhong;YIN Guangfu.Degradation of Residual Formaldehyde in Fabric by Photo-catalysis[J].武汉理工大学学报(材料科学版)(英文版),2008(02):147-150. |
[7] | Jiaguo Yu;Shuhan Wang;Jingxiang Low.Enhanced photocatalytlc performance of direct Z-scheme g-C3N4-TiO2 photocatalysts for the. decomposition of formaldehyde In air[J].Physical chemistry chemical physics: PCCP,201339(39):16883-16890. |
[8] | Koirala, Agni Raj;Docao, Son;Lee, Seong Beom;Yoon, Kyung Byung.Fate of methanol under one-pot artificial photosynthesis condition with metal-loaded TiO2 as photocatalysts[J].Catalysis Today,2015:235-250. |
[9] | Cremer, Till;Jensen, Stephen C.;Friend, Cynthia M..Enhanced Photo-Oxidation of Formaldehyde on Highly Reduced o-TiO2(110)[J].The journal of physical chemistry, C. Nanomaterials and interfaces,201450(50):29242-29251. |
[10] | Low, Wasu;Boonamnuayvitaya, Virote.Enhancing the photocatalytic activity of TiO2 co-doping of graphene-Fe3+ ions for formaldehyde removal[J].Journal of Environmental Management,2013:142-149. |
[11] | Ping Yang;Cheng Lu;Nanping Hua;Yukou Du.Titanium dioxide nanoparticles co-doped with Fe~(3+) and Eu~(3+) ions for photocatalysis[J].Materials Letters,20024(4):794-801. |
[12] | Huang DG;Liao SJ;Quan SQ;Liu L;He ZJ;Wan JB;Zhou WB.Preparation of anatase F doped TiO2 sol and its performance for photodegradation of formaldehyde[J].Journal of Materials Science,200719(19):8193-8202. |
[13] | 顾凌燕;王玉萍;彭盘英;王连军.S与金属共掺杂TiO2催化剂的制备及其光催化性能[J].中国有色金属学报,2009(5):910-918. |
[14] | 王金淑;邢朋飞;李莉莉;周美玲.机械化学法N掺杂纳米TiO2的制备与表征[J].北京工业大学学报,2006(7):633-637. |
[15] | 李强;杜记民;王爱志;王宝云.稀土-过渡金属共掺杂TiO_2纳米材料:结构和光催化性能[J].化工新型材料,2010(1):79-82. |
[16] | 柴瑜超;林琳;赵斌;何丹农.稀土掺杂二氧化钛光催化剂的研究进展[J].材料导报,2013(1):38-43,65. |
[17] | 井立强;张新;屈宜春;孙志华;李姝丹;蒋保江;付宏刚;孙家钟.掺杂镧的TiO2纳米粒子的光致发光及其光催化性能[J].中国稀土学报,2004(6):746-750. |
[18] | 钱斯文;王智宇;王民权.La3+掺杂对纳米TiO2微观结构及光催化性能的影响[J].材料科学与工程学报,2003(1):48-52. |
[19] | 水淼;岳林海;徐铸德.稀土镧掺杂二氧化钛的光催化特性[J].物理化学学报,2000(5):459-463. |
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