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采用X射线光电子能谱(XPS)、X射线衍射(XRD)、SEM、拉曼光谱等分析方法对国产低氧高碳型碳化硅纤维表面进行了研究。结果表明,纤维表面光滑、致密,以 SiCx Oy 组成为主、SiC 次之、SiO2最少,并有无定形碳存在。该纤维表面物理与化学特性有利于形成结合强度适中的复合材料界面,从而提高复合材料的强度和断裂韧性。

In this paper,X-ray photoelectron spectroscopy,X-ray diffraction,scanning electron microscopy and Raman spectroscopy were employed to study the surface physical and chemical properties of silicon carbide fi-bers with low oxygen and high carbon.Results show that fiber surface is smooth and compact,and disorderd free carbon exists in the surface of the fibers,which is in accordance with the chemical compositon of fibers.Al-so,the surface of fibers is mainly composed by SiOx Cy ,followed by SiC,and SiO2 .The fiber surface physical and chemical properties can help the combination of fibers and matrix with proper strength,which is beneficial to enhance the strength and improve the fracture toughness of the composite materials.

参考文献

[1] E. Buet;C. Sauder;S. Poissonnet.Influence of chemical and physical properties of the last generation of silicon carbide fibres on the mechanical behaviour of SiC/SiC composite[J].Journal of the European Ceramic Society,20123(3):547-557.
[2] Hinoki T.;Snead LL.;Katoh Y.;Hasegawa A.;Nozawa T.;Kohyama A..The effect of high dose/high temperature irradiation on high purity fibers and their silicon carbide composites[J].Journal of Nuclear Materials: Materials Aspects of Fission and Fusion,2002Pt.b(Pt.b):1157-1162.
[3] Hochet N.;Bunsell AR.;Berger MH..MICROSTRUCTURAL EVOLUTION OF THE LATEST GENERATION OF SMALL-DIAMETER SIC-BASED FIBRES TESTED AT HIGH TEMPERATURES[J].Journal of Microscopy,1997part 2(part 2):243-258.
[4] C. Sauder;A. Brusson;J. Lamon.Influence of Interface Characteristics on the Mechanical Properties of Hi-Nicalon type-S or Tyranno-SA3 Fiber-Reinforced SiC/SiC Minicomposites[J].International journal of applied ceramic technology,20103(3):291-303.
[5] Sebastien Bertrand;Philippe Forio;Rene Pailler;Jacques Lamon.Hi-Niaclon/SiC minicomposites with (pyrocarbon/SiC)n Nanoscale multilayered interphases[J].Journal of the American Ceramic Society,19999(9):2465-2473.
[6] Sebastien Bertrand;Rene Pailler;Jacques Lamon.Influence of Strong Fiber/Coating Interfaces on the Mechanical Behavior and Lifetime of Hi-Nicalon/(PyC/SiC)_n/SiC Minicomposites[J].Journal of the American Ceramic Society,20014(4):787-794.
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