实现手性化合物的有效分离是当前制药、化工、食品等领域急需解决的技术难题。作为手性拆分的重要方法之一，手性拆分膜的研究开发具有重要的学术和应用价值。对近年来国内外手性拆分膜的研究进展进行了综述，重点分析了其手性拆分原理、制备方法、国内外最新研究进展，以及目前存在的问题等，并且对手性拆分膜的未来发展方向进行了展望。
It is an urgent problem for effective separation of chiral compounds in the field of pharmaceutical, chemical,food and other fields.As one of the important methods of chiral separation,the research and develop-ment of chiral separation membrane has important academic and application value.In this work,the research progress of chiral separation membrane in China and abroad was reviewed.The chiral separation principle,prep-aration method,latest research progress and the existing problems were analyzed,and the future development direction of chiral separation membrane was discussed.
参考文献
| [1] | Ha, J.J.;Choi, H.J.;Jin, J.S.;Jeong, E.D.;Hyun, M.H..Liquid chromatographic resolution of proton pump inhibitors including omeprazole on a ligand exchange chiral stationary phase[J].Journal of chromatography, A: Including electrophoresis and other separation methods,201041(41):6436-6441. |
| [2] | Yujun Wang;Yu Hu;Jian Xu;Guangsheng Luo;Youyuan Dai.Immobilization of lipase with a special microstructure in composite hydrophilic CA/hydrophobic PTFE membrane for the chiral separation of racemic ibuprofen[J].Journal of Membrane Science,20071/2(1/2):133-141. |
| [3] | Kewen Tang;Litao Song;Yongbing Liu.Separation of flurbiprofen enantiomers by biphasic recognition chiral extraction[J].Chemical engineering journal,20103(3):411-417. |
| [4] | Zeineb Aturki;Martin G. Schmid;Bezhan Chankvetadze;Salvatore Fanali.Enantiomeric separation of new cathinone derivatives designer drugs by capillary electrochromatography using a chiral stationary phase, based on amylose tris(5-chloro-2-methylphenylcarbamate)[J].Electrophoresis: The Official Journal of the International Electrophoresis Society,201421/22(21/22):3242-3249. |
| [5] | Guo, R.;Li, K.;Cao, H.;Wu, X.;Wang, G.;Cheng, Z.;Wang, F.;Zhang, H.;Yang, H..Chiral polymer networks with a broad reflection band achieved with varying temperature[J].Polymer: The International Journal for the Science and Technology of Polymers,201025(25):5990-5996. |
| [6] | Meng, J.;Wei, G.;Huang, X.;Dong, Y.;Cheng, Y.;Zhu, C..A fluorescence sensor based on chiral polymer for highly enantioselective recognition of phenylalaninol[J].Polymer: The International Journal for the Science and Technology of Polymers,20112(2):363-367. |
| [7] | Maity, N.Ch.;Abdi, S.H.R.;Kureshy, R.I.;Khan, N.-U.H.;Suresh, E.;Dangi, G.P.;Bajaj, H.C..Chiral macrocyclic salen Mn(III) complexes catalyzed enantioselective epoxidation of non-functionalized alkenes using NaOCl and urea H _2O_2 as oxidants[J].Journal of Catalysis,20111(1):123-127. |
| [8] | 屈海涛;李峻青;武光顺;白建伟;张密林.淀粉苯基氨基甲酸酯类手性固定相的制备及用于HPLC手性体分离性能的研究[J].功能材料,2010(6):973-975,979. |
| [9] | Zhou, Z.-M.;Li, X.;Chen, X.-P.;Fang, M.;Dong, X..Separation performance and recognition mechanism of mono(6-deoxy-imino)- β-cyclodextrins chiral stationary phases in high-performance liquid chromatography[J].Talanta: The International Journal of Pure and Applied Analytical Chemistry,20102(2):775-784. |
| [10] | Pravin G. Ingole;Hari C. Bajaj;Kripal Singh.Membrane separation processes: Optical resolution of lysine and asparagine amino acids[J].Desalination: The International Journal on the Science and Technology of Desalting and Water Purification,2014:75-81. |
| [11] | Eiji Iritani;Nobuyuki Katagiri;Tsutomu Kawabata.Chiral separation of tryptophan by single-pass affinity inclined ultrafiltration using hollow fiber membrane module[J].Separation and Purification Technology,20093(3):337-344. |
| [12] | Kripal Singh;Pravin G. Ingole;Harshad Bhrambhatt.Preparation, characterization and performance evaluation of chiral selective composite membranes[J].Separation and Purification Technology,20112(2):138-146. |
| [13] | Wang, W.;Dong, X.;Nan, J.;Jin, W.;Hu, Z.;Chen, Y.;Jiang, J..A homochiral metal-organic framework membrane for enantioselective separation[J].Chemical communications,201256(56):7022-7024. |
| [14] | Nakagawa M;Ikeuchi Y;Yoshikawa M.Chiral separation of racemic amino acids with novel polyamides having N-alpha-acetyl-L-glutamyl residue as a diacid component[J].Polymer: The International Journal for the Science and Technology of Polymers,200821(21):4612-4619. |
| [15] | Kenta Shiomi;Masakazu Yoshikawa.Multi-stage chiral separation with electrospun chitin nanofiber membranes[J].Separation and Purification Technology,2013:300-304. |
| [16] | 李金苓;赵义平;张未来;王霞;陈莉;张青松.D-萘普生温敏分子印迹凝胶的制备及吸附性能研究[J].功能材料,2013(18):2693-2696,2705. |
| [17] | Sharon Fireman-Shoresh;Inna Popov;David Avnir;Sharon Marx.Enantioselective,Chirally Templated Sol-Gel Thin Films[J].Journal of the American Chemical Society,20058(8):2650-2655. |
| [18] | Wei WL;Guo BY;Lin JM.Ultra-high concentration of amylose for chiral separations in capillary electrophoresis[J].Journal of chromatography, A: Including electrophoresis and other separation methods,20099(9):1484-1489. |
| [19] | Jie Liu;Pascale Pham;Vincent Haguet;Fabien Sauter-Starace;Loic Leroy;Andre Roget;Emeline Descamps;Aurelie Bouchet;Arnaud Buhot;Pascal Mailley;Thierry Livache.Polarization-Induced Local Pore-Wall Functionalization for Biosensing: From Micropore to Nanopore[J].Analytical chemistry,20127(7):3254-3261. |
| [20] | Jing Zhu;Gang Sun.Facile Fabrication of Hydrophilic Nanofibrous Membranes with an Immobilized Metal-Chelate Affinity Complex for Selective Protein Separation[J].ACS applied materials & interfaces,20142(2):925-932. |
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