利用碳黑掺杂的方法制备熔融结合环氧(FBE)导电涂层,选用电化学阻抗谱法(EIS)、热重分析(TGA)和差示扫描量热(DSC)等手段研究了其在3%NaCl溶液中失效过程及防护机制.结果表明:与相应的含有少量碳黑的绝缘FBE涂层相比,导电FBE涂层体系的防护性能显著提高,这得益于导电涂层中碳黑连续网络增加了腐蚀介质的传输阻力;对涂层保护下金属基材腐蚀形貌的分析均证明了此结论.
参考文献
[1] | F Bueche. Electrical resistivity of conducting particles in an insulating matrix[J ]. J. Appl. Phys, 1972, 43: 4837. |
[2] | Tallman D E, Spinks G, Dominis A, et al, Ele ctoactive conducting polymers for corrosion control [ J ]. J. Solid State Electrochem, 2002, 6: 73. |
[3] | J - C Huang. Carbon Black Filled Conducting Polymers and Polymer Blends[ J ]. Adv Polym Tech, 2002,21: 299. |
[4] | J R Vilche, E C Bucharsky, C A Gudice. Application of EIS and SEM to evaluate the influence of pigment shape and content in ZRP formulations on the corrosion prevention of naval steel[ J ].Corros. Sci., 2002, 44:1287. |
[5] | H Marchebois, S Touzain, S Joiret et al. Zinc - rich powder coatings corrosion in sea water: influence of conductive pigments [J]. Prog. Org. Coat., 2002, 45:415. |
[6] | W K Lu, R L Elsenbaumer, B Wessling. Corrosion protection of mild steel by coatings containing polyanilline [J ]. Synth Met,1995,71:2163. |
[7] | M Fahlman, S Jasty, A J Epstein. Corrosion protection of iron/steel by emeraldine base polyaniline: An X - ray photoelectron spectroscopy study[J ]. Synth Met, 1997, 85:1323. |
[8] | Y Wei, J G Wang, X R Jia, et al. Polyaniline as corrosion protection coatings on cold rolled steel[ J ]. Polymer, 1995, 36: 4535. |
[9] | T Schauer, A Joos, L Dulog, et al. Protection of iron against corrosion with polyaniline primers [J ]. Prog Org Coat, 1998, 33:20. |
[10] | P J Kinlen, D C Silverman, C R Jeffreys, Corrosion protection using polyaniline coating formulations[ J ]. Synth Met, 1997, 85:1327. |
[11] | B. Wessling. Electrical Conductivity in Heterogeneous Polymer Systems Ⅴ ( 1 ): Further Experimental evidence for a Phase Transition at the Critical volume Concentration [ J ]. Polym. Eng.Sci, 1991,31:1200. |
[12] | D E Tallman, Y Pae, G P Bierwagen, Conducting polymers and Corrosion: Polyaniline on stell, Corrosion[ J ]. 1999, 55: 779. |
[13] | N V Krstajic, B N Grgur, S M Jovanovic et, al. Corrosion protection of mild steel by polypyrrole coatings in acid sulfate solutions[ J ]. Electrochim Acta, 1997, 42:1685. |
[14] | B. Wessling. Electrical Conductivity in Heterogeneous polymer systems( Ⅳ )[ 1 ] A new Dynamic Interfacial Percolation Model [J ]. Synth Met, 1988, 27 :A83. |
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