通过电化学测试方法研究了不同参数退火后Cu-30Ni合金管在静止人工海水中的腐蚀行为.结果表明,海水腐蚀初期,富Ni表面膜对Cu-30Ni合金管耐海水腐蚀性能的影响起主要作用,其相对于基体成为阳极性保护,且随着退火温度升高,保温时间延长.Cu-30Ni合金管抗蚀能力越好;随着海水浸泡时间的延长,退火后Cu-30Ni合金管的显微组织结构对海水腐蚀性能影响占优,细小的富Ni颗粒成为微电池的阳极,优先被腐蚀;720℃×30 min热处理后试样抗腐蚀性能较好,腐蚀40天后,没有发现点蚀坑.
参考文献
[1] | Shams AM,Din E I,Mohammed R A.Contribution to the problem of vapour-side corrosion of copper-nickel tubes in MSF distillers[J].Desalination,1998,115:135. |
[2] | Hodgkiess T,Vassiliou G.Complexities in the erosion corrosion of copper-nickel alloys in saline water[J].Desalination,2005,183:235. |
[3] | Al-Thubaiti M A,Hodgkiess T,Ho S Y K.Environmental influences on the vapourside corrosion of copper-nickel alloys[J].Desalination,2005,183:195. |
[4] | Pandey R K.Failure analysis of refinery tubes of overhead condenser[J].Engineering Failure Analysis,2006,13:739. |
[5] | Constantinides I,Adriaens A,Adams F.Surface characterization of artificial corrosion layers on copper alloy reference materials[J].Applied Surface Scicoce,2002,189:90. |
[6] | Yuan S J,Pehkonen S O.Surface characterization and corrosion behavior of 70Cu-30Ni alloy in pristine and sulfide-containing simulated seawater[J].Corrosion sciecce,2007,49:1276. |
[7] | Lin L Y,Zhao Y H.Study on grain boundary structures and corrosion behavior of copper alloys[J].Rare Metals,2000,19(4):301. |
[8] | Songbo Y,Li D Y.Effects of prior cold work on corrosion and corrosive wear of copper in HNO3 and NaCl solutions[J].MaAerials Science and Engineering A,2005,394:266. |
[9] | El-Dahshan M E.Corrosion and scaling problems present in some desalination plants in abu dhabi[J].Desalination,2001,138:371. |
[10] | Asrar N,Malik A U,Ahmad S,et al.Early failure of cupronickel condenser tubes in thermal desalination plant[J].Desalination.1998,116:135. |
[11] | Druska P,Strehblow H H,Golledge S.A surface analytical examination of passive layers on Cu/Ni alloys:Part I.Alkaline solution[J].Corrosion Science,1996,38(6):835. |
[12] | Zhao Y H,Wang X H,Lin L Y.Influence of mierostructure and surhme condition on antffouling property of 90Cu-10Ni alloy in seawater[J].Transaction of Nonferrous Metals Society of China,2001,14(4):563. |
[13] | Beccaria A M,Poggi G,Wang Y Z.Effect of heat treatments on Cu-30Ni70/30 alloy pitting susceptibility in sea water at different temperatures[J].Materials and Corrosion,1994,45:562. |
[14] | Zhu X,Lei T Q.Influence of deformation and heat treatment on seawater corrosion of 70Cu-30Ni alloy[J].Journal of Materials Science and Technology,1998,14:57. |
[15] | Zhu X L,Lei T Q.Characteristics and formation of corrosion product film of 70Cu-30Ni alloy in seawater[j].Corrosion Science,2002,44:67. |
[16] | 严宇民,林乐耘,朱小龙.残余应力对BFe30-1-1铜管耐蚀性能的影响[J].中国腐蚀与防护学报,1994,14(1):59. |
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