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用过氧化二苯甲酰做引发剂,聚乙烯醇做分散剂,以苯乙烯为单体,采用原位聚合的方法制备聚苯乙烯(PS)/纳米二硫化钼(MoS2)复合材料.应用示差扫描量热法(DSC)分析了不同MoS2含量时复合材料的热稳定性和玻璃化温度Tg;用高阻计测试了不同MoS2含量时复合材料的电性能.结果表明,加入MoS2,PS的Tg提高;且随着MoS2含量的增加,PS基体的热稳定性和玻璃化温度趋于稳定;复合材料的体积电阻率随着MoS2含量的增大而急剧降低,MoS2的含量增大到20%左右时,复合材料的体积电阻率达到108Ω*cm,已符合抗静电的要求.

参考文献

[1] Alexandre S Golub;Inna B Shumilova;Yan V Zubavichus et al.Layered compounds based on molybdenum disulfide and ruthenium arene complexes[J].Journal of Materials Chemistry,1997,7(01):163-167.
[2] Zhou X.;Frindt RF.;Yang D. .STUDY OF RESTACKED SINGLE MOLECULAR LAYER MOLYBDENUM DISULFIDE WITH ORGANIC TETRACHLOROETHYLENE INCLUDED[J].The journal of physics and chemistry of solids,1996(6/8):1137-1140.
[3] Rabin Bissessur;Robert I. Haines;Dean R. Hutchings;Ralf Bruning .Intercalation of a pendant-arm tetraazamacrocycle into molybdenum disulfide[J].Chemical communications,2001(17):1598-1599.
[4] L Wang;J Schindler;J A Thomas et al.Entrapment of polypyrrole chains between MoS2 layers via an in-situ oxidative polymerization encapsulation reaction[J].Chemistry of Materials,1995,10:1753-1755.
[5] N. Mirabal;P. Aguirre;M. A. Santa Ana;E. Benavente;Guillermo Gonzalez .Thermal stability and electrical conductivity in polyethers-molybdenum disulfide nanocomposites[J].Electrochimica Acta,2003(14/16):2123-2127.
[6] 刘维民;王延梅;田军 等.聚苯乙烯二硫化钼插层复合材料的制备方法[P].CN 02124645.9,2002-06-19.
[7] Gonzalez G.;Benavente E.;Santa Ana MA. .Mixed conductivity and lithium diffusion in poly(ethylene oxide) molybdenum disulfide nanocomposites[J].Electrochimica Acta,1998(10/11):1327-1332.
[8] Bissessur R.;Gallant D.;Bruning R. .Novel nanocomposite material consisting of poly [oxymethylene-(oxyethylene)] and molybdenum disulfide[J].Materials Chemistry and Physics,2003(2):316-320.
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