本文研究了多壁碳纳米管(MWNTs)在热固性钡酚醛树脂中的分散效果以及碳纳米管对酚醛树脂固化和炭化的影响.酚醛树脂含有丰富的苯环结构和丰富的羟基基团,能吸附在碳纳米管上起到均匀分散碳纳米管的作用.同时,碳纳米管能吸附进而调整酚醛树脂在其周围的排列,使酚醛树脂固化时有更多的碰撞机会从而促进酚醛树脂的固化,也使酚醛树脂炭化时能形成更多更完整的石墨结构,提高它在高温下的耐热性能.
参考文献
[1] | Ijima S .Helical microtubes of graphitic carbon[J].Nature,1991,354:56-58. |
[2] | Bethune D S;Kiang C H;de Vries M S et al.Cobalt-catalysed growth of carbon nanotubes with single-atomic-layer walls[J].Nature,1993,363:605-607. |
[3] | Tang Z;Xu H .Preparation,alignment and optical properties of soluble poly(phenylacetylene)-wrapped carbon nanotubes[J].Macromolecules,1999,32:2569-2576. |
[4] | Star A.;Liu Y.;Grant K.;Ridvan L.;Stoddart JF.;Steuerman DW.;Diehl MR.;Boukai A.;Heath JR. .Noncovalent side-wall functionalization of single-walled carbon nanotubes[J].Macromolecules,2003(3):553-560. |
[5] | Steuerman D W;Star A;Narizzano R et al.Interactions between conjugated polymers and single-walled carbon nanotubes[J].Journal of Physical Chemistry B,2002,106:3124-3130. |
[6] | Chen J;Liu H Y;Weimer W A et al.Noncovalent engineering of carben nanotube surfaces by rigid,functional conjugated polymers[J].Journal of the American Society,2002,124(903):40035. |
[7] | L. Valentini;D. Puglia;E. Frulloni .Dielectric behavior of epoxy matrix/single-walled carbon nanotube composites[J].Composites science and technology,2004(1):23-33. |
[8] | C.A.Martin;J.K.W.Sandler;A.H.Windle;M.-K.Schwarz;W.Bauhofer;K.Schulte;M.S.P.Skhaffer .Electric field-induced aligned multi-wall carbon nanotube networks in epoxy composites[J].Polymer: The International Journal for the Science and Technology of Polymers,2005(3):877-886. |
[9] | Yoon Jin Kim;Taek Sun Shin;Hyung Do Choi;Ho Gyu Yoon .Electrical conductivity of chemically modified multiwalled carbon nanotube/epoxy composites[J].Carbon: An International Journal Sponsored by the American Carbon Society,2005(1):23-30. |
[10] | F.H. GOJNY;K. SCHULTE .Functionalisation effect on the thermo-mechanical behaviour of multi-wall carbon nanotube/epoxy-composites[J].Composites science and technology,2004(15):2303-2308. |
[11] | 苏志强,刘云芳,魏强,张洋,沈曾民.碳纳米管改性酚醛树脂的研究[J].炭素技术,2002(01):8-11. |
[12] | 张彬,马仁志,徐才录,魏秉庆,梁吉,吴德海.双电层电容器碳纳米管固体极板的制备[J].电子学报,2000(08):13-15. |
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