欢迎登录材料期刊网

材料期刊网

高级检索

通过强酸处理方法对碳纳米管进行改性处理并对其结构和分散稳定性进行分析.采用溶液共混法制备了聚氨酯/碳纳米管复合材料.利用FTIR对其结构进行了分析,探讨了碳纳米管对复合材料力学性能、热稳定性能以及弹性回复率的影响.结果表明,碳纳米管经酸处理后添加了羧酸活性基团,提高了其在溶剂中的分散性;在复合材料中,碳纳米管以较强氢键与大分子连接,复合材料的力学性能和热稳定性能都有所提高,而弹性回复率没有受到很大影响.

参考文献

[1] Iijima S .Helical microtubules of graphitic carbon[J].Nature,1991,354:56-58.
[2] T.-E.Chang;A.Kisliuk;S.M.Rhodes .Conductivity and mechanical properties of well-dispersed single-wall carbon nanotube/polystyrene composite[J].Polymer: The International Journal for the Science and Technology of Polymers,2006(22):7740-7746.
[3] Xiong Jiawen;Zheng Zhen;Qin Xiumin et al.The thermal and mechanical propertiea of a polyurethane/multi-walled carbon nanotube composite[J].Carbon,2006,44:2701-2707.
[4] Park C.;Ounaies Z.;Watson KA.;Crooks RE.;Smith J.;Lowther SE. Connell JW.;Siochi EJ.;Harrison JS.;Clair TLS. .Dispersion of single wall carbon nanotubes by in situ polymerization under sonication[J].Chemical Physics Letters,2002(3-4):303-308.
[5] Chen J;Mark A H;Hu H et al.Solution pmporties of singlewalled carbon nanotubes[J].Science,1998,282:95-98.
[6] Nanda Gopal Sahoo;Yong Chae Jung;Hye Jin Yoo;Jae Whan Cho .Influence of carbon nanotubes and polypyrrole on the thermal, mechanical and electroactive shape-memory properties of polyurethane nanocomposites[J].Composites science and technology,2007(9):1920-1929.
[7] Hualong Pan;Luqi Liu;Zhi-Xin Guo;Liming Dai;Fushi Zhang;Baoben Zhu;Richard Czerw;David L. Carroll .Carbon Nanotubols from Mechanochemical Reaction[J].Nano letters,2003(1):29-32.
[8] Liang-Siong Teo;Chuh-Yung Chen;Jen-Feng Kuo .Fourier transform infrared spectroscopy study on effects of temperature on hydrogen bonding in amine-containing polyurethanes and poly(urethane-urea)a[J].Macromolecules,1997,30:1793-1799.
[9] 李绍雄;朱吕民.聚氨酯树脂[M].南京:江苏科学技术出版社,1992:38.
上一张 下一张
上一张 下一张
计量
  • 下载量()
  • 访问量()
文章评分
  • 您的评分:
  • 1
    0%
  • 2
    0%
  • 3
    0%
  • 4
    0%
  • 5
    0%