欢迎登录材料期刊网

材料期刊网

高级检索

莫来石陶瓷材料作为高性能集成电路的候选材料,在电子封装基片领域有着广阔的应用前景,但过高的烧结温度限制了其发展.本文利用溶胶-凝胶法制备能够在低温实现烧结的硼硅酸盐玻璃,作为引入相以实现莫来石陶瓷封装材料的低温共烧,通过研究CaO、B2O3、SiO2的不同组成并引入ZnO、P2O5作为助烧剂,最终制得了能够在800℃实现低温烧结的硼硅酸盐玻璃,其线性收缩率约为22.4%~24.0%,表观密度为2.21+/-0.1,ε=4.1+/-0.2,tgδ<0.06%,Rj>1.0×1012Ω·cm.

参考文献

[1] Tamura Shinichi .Glass fiber having low dielectric co-nstant[P].JP 10120437A212,1998-05.
[2] 田民波.电子封装工程[M].北京:清华大学出版社,2003:258.
[3] 干福熹.现代玻璃科学技术[M].上海:上海科学技术出版社,1990:394.
[4] 蔡伟,江涛,谭小球,魏群,李燕.低温烧结低介硅灰石瓷料的研制[J].电子元件与材料,2002(02):16-18.
[5] 崔茂林.玻璃工艺学[M].咸阳:陕西科技大学出版社,1982:19-21.
[6] Shao-hong Wang;He-ping Zhou .Densification and dielectric properties of CaO-B_2O_3-SiO_2 system glass ceramics[J].Materials Science & Engineering, B. Solid-State Materials for Advanced Technology,2003(1/3):597-600.
[7] Jean Jau-ho;Kuan Tong-hua;Chang Chia-ruey .Low-temperature-fired,low-dielectric-constant silica glass composite for substrate application[J].Materials Chemistry and Physics,1995,41:123-127.
[8] Chia-Ruey Chang;Jau-Ho Jean .Crystallization kinetics and mechanism of low-dielectric, low-temperature, cofirable CaO-B{sub}2O{sub}3-SiO{sub}2 glass-ceramics[J].Journal of the American Ceramic Society,1999(7):1725-1732.
[9] Cheng-Dao Lei;Jau-Ho Jean .Effect of Crystallization on the Stress Required for Constrained Sintering of CaO-B_2O_3-SiO_2 Glass-Ceramics[J].Journal of the American Ceramic Society,2005(3):599-603.
[10] Alizadeh P;Marghussian V K .The effect of cornpositional changes on the crystallization behaviour and mechanical properties of diopside-wollastonite glass-ceramics in the SiO2-CaO-MgO(Na2O)system[J].Journal of the European Ceramic Society,2000,20:765-773.
[11] Muralidhar S K;Roberts G J;Parma et al.Low dielectric,low temperature fired glass ceramics[P].US 5258335,1993.
上一张 下一张
上一张 下一张
计量
  • 下载量()
  • 访问量()
文章评分
  • 您的评分:
  • 1
    0%
  • 2
    0%
  • 3
    0%
  • 4
    0%
  • 5
    0%