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通过改进的Hummers法制备氧化石墨,将获得的氧化石墨进行热剥离以及超声剥离得到双层甚至单层的氧化石墨烯片.然后采用化学还原-水合肼还原的方法去除氧化石墨烯所含的羧基COOH、羟基OH、羰基C=O和环氧基等化学基团.本实验着重研究了还原剂的用量和反应时间对各个化学基团的影响规律.

参考文献

[1] Novoselov K S;Geim A K;Morozov S V et al.Electric field effect in atomically thin carbon films[J].Science,2004,306(5696):666-669.
[2] Geim AK;Novoselov KS .The rise of graphene[J].Nature materials,2007(3):183-191.
[3] Michael J.McAllister;Je-Luen Li;Douglas H.Adamson .Single Sheet Functionalized Graphene by Oxidation and Thermal Expansion of Graphite[J].Chemistry of Materials: A Publication of the American Chemistry Society,2007(18):4396-4404.
[4] Jeffrey T P;Ted B;George C S .Computational studies of the structure,behavior upon heating,and mechanical properties of graphite oxide[J].Physical Chemistry,2007,111(49):18099-18111.
[5] K. S. Novoselov;D. Jiang;F. Schedin;T. J. Booth;V. V. Khotkevich;S. V. Morozov;A. K. Geim .Two-dimensional atomic crystals[J].Proceedings of the National Academy of Sciences of the United States of America,2005(30):10451-10453.
[6] Berger, C;Song, ZM;Li, XB;Wu, XS;Brown, N;Naud, C;Mayo, D;Li, TB;Hass, J;Marchenkov, AN .Electronic confinement and coherence in patterned epitaxial graphene[J].Science,2006(5777):1191-1196.
[7] Minghui Liang;Bin Luo;Linjie Zhi .Application of graphene and graphene-based materials in clean energy-related devices[J].International journal of energy research,2009(13):1161-1170.
[8] Horiuchi S et al.Carbon nanofilm with a new structure and property[J].Applied Physics,2003,42:1073-1076.
[9] Graeme W;Brian S;Prashant V K .TiO2-Graphene nanocomposites.UV-Assisted photocatalytic reduction of graphene oxide[J].American Chemical Society,2008,2(07):1487-1491.
[10] Pinggui Liu;Kecheng Gong .Synthesis of polyaniline-intercalated graphite oxide by an in situ oxidative polymerization reaction[J].Carbon: An International Journal Sponsored by the American Carbon Society,1999(4):706-707.
[11] 傅玲,刘洪波,邹艳红,李波.Hummers法制备氧化石墨时影响氧化程度的工艺因素研究[J].炭素,2005(04):10-14.
[12] Li D;Muller MB;Gilje S;Kaner RB;Wallace GG .Processable aqueous dispersions of graphene nanosheets[J].Nature nanotechnology,2008(2):101-105.
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