一维纳米TiO2由于比表面积大,长径比高,在工业废水处理中既能充分发挥TiO2的光催化活性,又易分离,故开展TiO2一维纳米材料的研究有重要价值.本文确定了制备TiO2纳米棒最优的工艺条件,用XRD、SEM、FT-IR、TGA-DSC对产物的结构与性能进行了表征.所制备的纳米TiO2呈棒状且为锐钛矿型.利用紫外光催化降解甲基橙的效果考察了这种光催化剂的活性,结果表明,其降解率较用sol-gel法制备的TiO2粉末的降解率提高了10%左右.
参考文献
[1] | Kominami H;Muratami S;Kato J et al.Correla-tion between some physical propertiesof titanium dioxide particles and their photocatalytic activity for some probe reactions in aqueous systems[J].Journal of Physical Chemistry B,2002,106(40):10501-10507. |
[2] | 徐淑丽,张兴堂,刘兵,杜祖亮,张治军.模板-电泳沉积法制备TiO2纳米棒[J].化学研究,2006(02):50-52. |
[3] | Ruzica R. Djenadic;Ljubica M. Nikolic;Konstantinos P. Giannakopoulos .One-dimensional titanate nanostructures: Synthesis and characterization[J].Journal of the European Ceramic Society,2007(13/15):4339-4343. |
[4] | Li XL;Peng Q;Yi JX;Wang X;Li YD .Near monodisperse TiO2 nanoparticles and nanorods[J].Chemistry: A European journal,2006(8):2383-2391. |
[5] | Kim C S;Moon B K;Park J H et al.Solvotherinal synthesis of nanocrystalline TiO2 in toluene with surfactant[J].Journal of Crystal Growth,2003,257:309-315. |
[6] | P. D. Cozzoli;R. Comparelli;E. Fanizza;M. L. Curri;A. Agostiano .Photocatalytic activity of organic-capped anatase TiO_2 nanocrystals in homogeneous organic solutions[J].Materials science & engineering, C. Biomimetic and supramolecular systems,2003(6/8):707-713. |
[7] | Drelich J.;Chen LY.;Miller JD.;Guruswamy S.;Lu YQ. .FTIR internal reflection spectroscopy studies of the effect of pH on adsorption of oleate oleic acid at the surface of a TiO2 thin film deposited on a Ge single crystal[J].Applied Surface Science: A Journal Devoted to the Properties of Interfaces in Relation to the Synthesis and Behaviour of Materials,1998(2):236-244. |
[8] | Kiyoshi Kanie;Tadao Sugimoto .Shape control of anatase TiO_2 nanoparticles by amino acids in a gel–sol system[J].Chemical communications,2004(14):1584-1585. |
[9] | 李秀艳,杨贤锋,吴明娒.不同介质中水热合成纳米TiO2粉体及其光催化性能研究[J].无机材料学报,2008(06):1253-1258. |
[10] | 李谦,周大鹏,孙蓉,祝迎春,张治军.有机酸修饰溶胶/凝胶法制备的二氧化钛纳米薄膜的表征[J].河南大学学报(自然科学版),2001(02):56-58. |
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