以Mo、Fe、Cr、Ni和不同粒度的FeB粉为原料,采用反应硼化烧结法制备了Mo2FeB2基金属陶瓷.研究了FeB粉粒度对金属陶瓷硬质相形貌及力学性能的影响.结果表明:当FeB粉较粗时,在固相反应阶段生成的Mo2FeB2硬质相颗粒较粗,并在随后的液相烧结过程中沿c轴优先生长,最终呈粗大的长条状;当FeB粉较细时,固相反应进行较完全,生成的硬质相颗粒细小,其Mo含量相对较高,晶格常数c与a之间差距缩小,各向异性减小,硬质相沿c轴的生长得到抑制,最终呈细小的近等轴状.当硬质相呈近等轴状时,由于硬质相颗粒平均尺寸较小,金属陶瓷具有较高的抗弯强度和硬度;当硬质相呈长条状时,金属陶瓷具有较好的断裂韧性,其增韧机制主要为裂纹偏转和颗粒桥接.
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