采用真空烧结工艺制备板状WC晶粒硬质合金,在800～1 200℃条件下以不同升温速率升温.采用XRD、SEM、EDS研究了固相烧结的升温速率对其显微组织及力学性能的影响.研究结果表明:在800～1 200℃温度区间内,随着升温速率的降低,硬质合金的硬度、抗弯强度、断裂韧性均有所提高;其中,随着800～1 000℃的升温速率的降低,硬质合金最终烧结体的组织变得均匀,二维结构中硬质相的晶粒长厚比升高,材料硬度提高趋势较大;随着1 000～1 200℃的升温速率的降低,硬质相晶粒细化,粘结相中固溶合金元素含量增加,材料抗弯强度提高的幅度较明显;同时降低800～1 000℃和1 000～1 200℃的升温速率,可使裂纹长度减小,裂纹偏转增强,大幅提高材料的断裂韧性.在800～1 200℃以2℃/min升温得到的烧结体可获得较均匀的显微组织,硬质相颗粒大部分呈板条状且颗粒长厚比较大,烧结体具有较好的力学性能.
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