通过SEM,XRD,FTIR和电化学的方法,研究了硝酸铈对6061铝合金磷化过程的影响,并对铝合金磷化动力学行为进行了探讨.结果表明,硝酸铈的加入使得在铝合金表面上所形成的磷化膜结晶细化,成膜速度加快,磷化完成时间缩短.磷化膜组成为Zn3(PO4)2*4H2O和Zn2Fe(PO4)2*4H2O,硝酸铈并没有构成磷化膜的组成成分,硝酸铈在铝合金磷化过程中起到了形核与促进磷化的作用.
参考文献
[1] | 安茂忠,屠振密,杨哲龙,张景双,王家林.稀土化合物在磷化中的影响和作用[J].材料保护,2000(11):20-21,28. |
[2] | 周谟银 .锌系磷化对铝材涂装的意义[J].上海电镀,1998,2:2-4. |
[3] | Susac D;Sun X;Li RY;Wong KC;Wong PC;Mitchell KAR;Champaneria R .Microstructural effects on the initiation of zinc phosphate coatings on 2024-T3 aluminum alloy[J].Applied Surface Science: A Journal Devoted to the Properties of Interfaces in Relation to the Synthesis and Behaviour of Materials,2004(1):45-59. |
[4] | Sun X.;Susac D.;Li R.;Wong KC.;Foster T.;Mitchell KAR. .Some observations for effects of copper on zinc phosphate conversion coatings on aluminum surfaces[J].Surface & Coatings Technology,2002(1):46-50. |
[5] | Badawy W A;Al-kharafi F M;Ei-azab A S .Electrochemical behaviour and corrosion inhibition of Al-l26061 and Al-Cu in neutral aqueous solutions[J].Corrosion Science,1999,41:709-727. |
[6] | 王成,江峰,林海潮.Al合金表面铬酸盐处理及替代工艺研究进展[J].腐蚀科学与防护技术,2001(06):347-350. |
[7] | Chhiu-Tsu Lin .Green chemistry in situ phosphatizing coatings[J].Progress in Organic Coatings: An International Review Journal,2001(3/4):226-235. |
[8] | Mary C. Whitten;Valicia J. Burke;Heather A. Neuder;Chhiu-Tsu Lin .Simultaneous Acid Catalysis and in Situ Phosphatization Using a Polyester-Melamine Paint: A Surface Phosphatization Study[J].Industrial & Engineering Chemistry Research,2003(16):3671-3679. |
[9] | 谢守德,李新立.涂装打底用铝件磷化发展概况[J].上海涂料,2004(06):16-19. |
[10] | 吴素珍.化学转化膜[M].北京:机械工业出版社,1988:150. |
[11] | 暨调和;黄季煌 .常(低)温加速磷化过程φ-t曲线的研究[J].电镀与环保,1994,14(04):11-14. |
[12] | 邝钜炽.锌系磷化的稀土促进成膜机理研究[J].稀土,2006(01):26-29. |
[13] | 张圣麟,李红玲,娄淑芳,孔小波.一种低温锌系磷化促进剂的动力学研究[J].表面技术,2006(06):40-42,81. |
[14] | 卢涌泉;邓振华.实用红外光谱解析[M].北京:电子工业出版社,1989:210-244. |
[15] | Ghaili;Potvin R J A .The mechanism of phosphating of steel[J].Corrosion Science,1972,12:583-598. |
上一张
下一张
上一张
下一张
计量
- 下载量()
- 访问量()
文章评分
- 您的评分:
-
10%
-
20%
-
30%
-
40%
-
50%