机动车尾气排放造成的污染是倍受国际社会关注的问题,开发具有自主产权的机动车尾气净化催化技术是我国控制城市大气污染的重要措施.本研究采用"超声膜扩散"法制备了(LnO2)x-(ZrO2)1-x(Ln=Ce,Pr,Tb; x=0.4~0.9)储氧材料,对其储氧量、热稳定性、催化特性和抗老化性能进行了测量.结果表明,(LnO2)x-(ZrO2)1-x(Ln = Pr, Tb)显示出优于(CeO2)x-(ZrO2)1-x的综合性能,是机动车尾气净化三元催化重要的候选材料.
参考文献
[1] | Shi Z M;Liu Y;Yang W Y et al.Evaluation of cordierite-ceria composite ceramics with oxygen storage capacity[J].Journal of the European Ceramic Society,2002,22:1251-1256. |
[2] | M.Lopez Granados;F.Cabello Galisteo;P.S.Lambrou;R.Mariscal;J.Sanz .Role of P-containing species in phosphated CeO_2 in the deterioration of its oxygen storage and release properties[J].Journal of Catalysis,2006(2):410-421. |
[3] | Murota T;Hasegawa T;Aozasa S .Production method of cerium oxide with high storage capacity of oxygen and its mechanism[J].Journal of Alloys and Compounds,1993,193:298-299. |
[4] | Eleonora Aneggi;Marta Boaro;Carla de Leitenburg;Giuliano Dolcetti;Alessandro Trovarelli .Insights into the dynamics of oxygen storage/release phenomena in model ceria-zirconia catalysts as inferred from transient studies using H_2,CO and soot as reductants[J].Catalysis Today,2006(1/4):94-98. |
[5] | Dutta G;Waghmare UV;Baidya T;Hegde MS;Priolkar KR;Sarode PR .Origin of enhanced reducibility/oxygen storage capacity of Ce1-xTixO2 compared to CeO2 or TiO2[J].Chemistry of Materials: A Publication of the American Chemistry Society,2006(14):3249-3256. |
[6] | Mamontov E;Egami T;Brezny R et al.Lattice defects and oxygen storage capacity of nanocrystalline ceria and ceria-zirconia[J].Journal of Physical Chemistry B,2000,104:11110-11116. |
[7] | Mai H;Sun L;Zhang Y et al.Shape-selective synthesis and oxygen storage behavior of ceria nanopolyhedra,nanorods,and nanocubes[J].Journal of Physical Chemistry B,2005,109:24380-24385. |
[8] | Tsinoglou D N;Koltsakis G C;Peyton Jones J C .Transient modelling of flow distribution in automotive catalytic converters[J].Industrial and Engineering Chemistry Research,2002,41:1152-1165. |
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