评述Pd与RE金属的相互作用与合金化行为,包括固溶度、共晶反应、包晶反应及各中间相的形成和稳定性.RE金属在Pd中有反常高的固溶度,并与一个综合参数Nf/ΔX(rR-rPd)成正比;在Pd-RE系中出现12种化学计量化合物和19种晶体结构,6个共晶系14种共晶反应式和9种包晶反应式.绘制了富Pd端简约共晶温度图和主要中间相的简约转变温度图,在简约转变温度对RE原子半径的图上观察到强的相似性和Ce、Eu和Yb的反常性.提出了RE在Pd中固溶度和简约共晶温度Teu/Tr对RE原子半径变化的判据,扩展了Hume-Rothery和Raynor等人的相应判据.
参考文献
| [1] | 何纯孝;马光辰;王文娜.贵金属合金相图[M].北京:冶金工业出版社,1983 |
| [2] | 何纯孝;周月华;王文娜.贵金属合金相图[M].北京:冶金工业出版社,1993 |
| [3] | Massalski T B;OKamoto H .Binary Alloy Phase Diagrams[Z].ASM International,Materials Park,OH,1990. |
| [4] | Savitsky E;Polyakova V;Gorina N;Savin I.V..Physical Metallurgy of Platinum Metals[M].Moscow:MIR publishers,1978 |
| [5] | СавицкийЕ М;Ълагородны;Справоцник;Металлргия .[Z].Москва,1984. |
| [6] | OKamoto H .Palladium-yttrium systems[J].Journal of Phase Equilibria,1991,12(02):252. |
| [7] | 张康侯;陈藜莉 .含50-100at% Pd的Ce-Pd相图[J].化学学报,1989,47:592. |
| [8] | Zhang Kanghou;Chen Lili .The phase diagram of Pd-Pr below 50 at% Pr[J].Journal of Alloys and Compounds,1992,184:L9. |
| [9] | Chen Lili;Zhang Kanghou .Phase diagrom of Nd-Pd(Nd≤50 at%)binary system[J].Acta Metallurgica Sinica(English Letters),1991,4(01):B356. |
| [10] | Chen Lili;Zhang Kanghou .Phase diagrom of Nd-Pd(Nd≤50 at%)binary system[J].金属学报,1991,27(01):B17. |
| [11] | Chen Nian-Yi;Xu Hua;Ning Yuantao.[J].Journal of Molecular Science,1981(02):115. |
| [12] | Ning Yuantao;Zhou Xinming;Zheng Yun et al.The prediction and synthesis of some new intermetallic compounds between transition metals and rare earth metals[J].Journal of the Less-Common Metals,1989,147:167. |
| [13] | Harris I R;Norman M .The Electronic state of Ce in some Pd alloys[J].Journal of the Less-Common Metals,1968,15:285. |
| [14] | Norman M;Harris I R .A study of some α Pd-Sc,-Zr and -Gd alloys[J].Journal of the Less-Common Metals,1969,18:333. |
| [15] | Thompson J R .The system thorium-pallaclium[J].Journal of the Less-Common Metals,1964,6:94. |
| [16] | 文飞,宁远涛,赵怀志.微量稀土元素对钯的组织结构之影响[J].贵金属,1992(03):10-16,41. |
| [17] | Ning Yinan;Ning Yuantao .Factors influencing solid solubilities of rare-earths in Pd[J].Acta Metallurgica Sinica(English Letters),1997,10(04):318. |
| [18] | Boom R;De Boer F R;Miedema A R .On the heat of mixing of liquid alloys(Ⅱ)[J].Journal of the Less-Common Metals,1976,46:271. |
| [19] | Bretschneider T;Schaller H-J .The constitution of Pd-Ce alloys[J].Zeitschrift fur Metallkunde,1990,81(02):84. |
| [20] | Pauling L .Electron transfer in intermetallic compounds[J].Proceedings of the National Academy of Sciences of the United States of America,1950,36:533. |
| [21] | Gschneidner Jr K A;Waber J T;Spedding F H;Daane A H.The Rare Earths[M].John Wiley & Sons Inc,1961:386. |
| [22] | Ning Yinan;Ning Yuantao .Alloying behaviour and atomic sise effect in palladium-rich Pd-RE systems[J].Journal of Materials Science and Technology,1997,13(01):21. |
| [23] | Gschneidner Jr K A;Calderwood F W .Silver-Rare Earth system[J].Bulletin of Alloy Phase Diagrams,1983,4(04):364. |
| [24] | Doyle M L;Harris I R .Palladium-rare earth alloys[J].Platinum Metals Review,1998,32(03):130. |
| [25] | Takao K;Sakamoto Y;Yoshid M .Order-disorder transitions of the Pd7Dy(Y)phases in Pd-Dy(Y)alloys[J].Journal of the Less-Common Metals,1989,152:115. |
| [26] | Sakamoto Y;Takao K;Ohmaki M .The phase transitions in the Pd-Ce alloy system[J].Journal of the Less-Common Metals,1990,162:343. |
| [27] | Sakamoto Y;TaKao K;Takeda S .Evidence for an ordered Pd7Sm phase in Pd-Sm alloys[J].Journal of the Less-Common Metals,1989,152:127. |
| [28] | Takao K;Zhao K L;Sakamoto Y .Obeservations of an ordered Pd7Eu phase in Pd-Eu alloys[J].Journal of Materials Science,1990,25:1255. |
| [29] | Sakamoto Y;Takao K;Yashida M et al.Evidence for an ordered Pd7Gd phase in Pd-Gd alloys[J].Journal of the Less-Common Metals,1988,143:207. |
| [30] | Takao K;Sakamoto Y;Araki T et al.Observations of ordered Pd7RE(RE=Tb,Tm,Yb,Lu)phases in Pd-RE alloys[J].Journal of Alloys and Compounds,1993,193:41. |
| [31] | Sakamoto Y;Takao K;Nagaoka Y.[J].Journal of Materials Science Letters,1991(10):341. |
| [32] | Zhang Kanghou;Chen Lili .Crystal lattices of SmPd5 and EuPd5[J].Acta Metallurgica Sinica(English Letters),1988,1(01):B75. |
| [33] | Contardi V;Marazza R;Rambaldi G et al.A contribution to coupled reaction of rare earth oxides with Pd and H[J].Zeitschrift fur Metallkunde,1991,82(03):169. |
| [34] | Palenzoza A;Iandelli A .The crystal structure and lattice constants of RE3Pd4,Y3Pd4 and Th3Pd4 compounds[J].Journal of the Less-Common Metals,1974,34:121. |
| [35] | 宁远涛.贵金属与稀土金属的相互作用（Ⅰ）Au-RE系[J].贵金属,2000(01):42-51. |
| [36] | 宁远涛.贵金属与稀土金属的相互作用：（Ⅱ）Ag-RE系[J].贵金属,2000(02):46-56,62. |
| [37] | Darken L S;Gurry R W.Physical Chemistry of Metals[M].New York:McGraw-Hill Book Co,1953 |
| [38] | Gschneidner Jr K A;Calderwood F W;Gschneidner Jr K A;Eyring L.In Handbook on the Physics and Chemistry of Rare Earths[M].Amsterdam:North-Holland Physics Published Company,1986:1. |
| [39] | Rider P E;Gschneidner Jr K A;Mcmasters O D .[J].Trams TMS-AIME,1965,233(08):1488. |
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