研究了阴离子表面活性剂疏水链的长度对光化学制备金纳米粒子的影响.结果发现,疏水链越长,获得的金纳米粒子的尺寸越小;特别是苯环的引入使诱导和自催化现象越加不明显.在十二烷基磺酸钠体系中获得的金纳米粒子的λmax位于540.7nm,TEM表征的平均粒径为47.1nm;十二烷基苯磺酸钠体系的λmax位于526.5nm,平均粒径为6.7nm.探讨了胶束性质对光化学制备金纳米粒子的影响.
参考文献
| [1] | Dr Robert Whetten;Dr Gregory;Schaaf John Tom .Gold nanoclusters can be left- handed or right- handed[EB/OL].http://unisci.com |
| [2] | Stephan Link;Mostafa A El-Sayed .Spectral properties and relaxation dynamics of surface plasmon electronic oscillations in gold and silver nanodots and nanorods[J].Journal of Physical Chemistry B,1999(103):8410-8246. |
| [3] | Masatake Haruta;Masakazu Date .Advances in the catalysis of Au nanoparticles[J].Applied Catalysis, A. General: An International Journal Devoted to Catalytic Science and Its Applications,2001(1/2):427-437. |
| [4] | 蒋治良,冯忠伟,李廷盛,李芳,钟福新,谢济运,义祥辉.金纳米粒子的共振散射光谱[J].中国科学B辑,2001(02):183-188. |
| [5] | Schonenberger C;Van Der Zande B M I;Fokkink L G J et al.Fabrication, characteration, and optical properties of gold nanoparticles/porous alumina compositions; the nonscattering maxwell - gemett limit[J].Journal of Physical Chemistry B,1997,101:1548-1555. |
| [6] | Lyadimia M Bronstein;Dmitri M Chernyshov;Peter M Valetsky .Metal nanoparticles grown in the nanostrutured matrix of poly (octadecylsiloxane)[J].Langmuir,2000,16(22):8221-8225. |
| [7] | Zhou Y;Wang C Y;Zhu Y R et al.A novel ultraviolet irradation technique for shape - controlled synthesie of gold nanoparticles at room temperature[J].CHEMISTRY OF MATERIALS,1999,11:2310-2312. |
| [8] | BRONSTEIN L;chemyshov D;Valetsky P .Laser photolysis formation of gold colloidal in block copolymer nicelles[J].Langmuir,1999,15(01):83-91. |
| [9] | Esumi K;Matshuhisa K;Torigoe K .Preparation of rodlike gold particles by UV irradation using cationic micelles as a template[J].Langmuir,1995,11:3285-3287. |
| [10] | 潘善林,张浩力,彭勇,王臻,力虎林.模板合成法制备金纳米线的研究[J].高等学校化学学报,1999(10):1622-1624. |
| [11] | Torigoe K;Esumi K .Preparation of colloidal gold by photochemical of AuCl4 cationc surfactant complexes[J].Langmuir,1992,8:59-63. |
| [12] | Carrot G M;Valmalette J C;Plummer C J G et al.Gold nanoparticles synthesis in graft copolymer micelles[J].Colloid and Polymer Science,1998,276:853-859. |
| [13] | Henglei A .Physicochemical properties of small metal particles in solution: microelectrode reaction, chemisorption, composite metal particles, and the atom- to - metal transition[J].Journal of Physical Chemistry,1993,97:5457-5487. |
| [14] | Kaushik Mallik;Madhuri Mandal;Narayan Pradhan et al.Seed mediated formation of bimetallic nanoparticles by UV irradation: a photochemical approach for the prepatration of "core-shell" type structures[J].Nano Letters,2001,1(06):319-233. |
| [15] | Remita S;Archirel P;Mostufavl M .Evaluation of the redox potential of Ag1 I (CN)22-/Ag10(CN) 22- in aqueous solution[J].Journal of Physical Chemistry,1995(99):13198-13202. |
| [16] | Takeuchi Y;Ida T;Kimura K .Colloidal stability of gold nanoparticles in 2 - propanol under laser irradiation[J].Journal of Physical Chemistry B,1997,101(08):1322-1327. |
| [17] | Andrey L Rogach;Gvidona P Shevchenko;Zinaida M Afans' eva et al.Change in the morphology and optical absorption of colloidal silver reduced with formic acid in the polymer matrix under UV irradation[J].Journal of Physical Chemistry B,1997,101:8129-8132. |
| [18] | 李葵英.界面与胶体的物理化学[M].哈尔滨:哈尔滨工业大学出版社,1998:183-212. |
| [19] | Huang H H;Ni X P;Chew G L et al.Photochemical formation of silver nanoparticles in poly (n - vinylpyrrolidone)[J].Langmuir,1996,12(04):909-912. |
| [20] | 陈宗淇;戴闽光.胶体化学[M].北京:高等教育出版社,1984:308-314. |
上一张
下一张
上一张
下一张
计量
- 下载量()
- 访问量()
文章评分
- 您的评分：
-
10%
-
20%
-
30%
-
40%
-
50%