考察了Pd、Pt、Pd-Rh和Pt-Rh对天然气汽车尾气净化催化剂的影响.制备了以La-Al2O3、La-Al2O3+Ce2O-ZrO2和La-Al2O3+CeO2-ZrO2-MnOx为载体的天然气汽车尾气净化钯催化剂.结果表明,Pd/Al2O3+CeO2-ZrO2-MnOx催化剂能极大地降低CH4的起燃温度并显著改善催化剂的反应性能.该催化剂经1000℃水热老化后,CH4的起燃温度仅上升了40℃,表现出优异的抗老化性能.
参考文献
[1] | Hell K H;Piotrowski G K;Schaefer R M .Evaluation of specialized methane catalytic converters on a CNG-fueled vehicle[R].SAE. Paper. 940473 |
[2] | Subramannian .Treating emissions from engines fueled by compressed natural gas[P].US:5176887,1993. |
[3] | Jordan K. Lampert;M. Shahjahan Kazi;Robert J. Farrauto .Palladium catalyst performance for methane emissions abatement from lean burn natural gas vehicles[J].Applied Catalysis, B. Environmental: An International Journal Devoted to Catalytic Science and Its Applications,1997(3/4):211-223. |
[4] | Burch R;Anita Ramli .A comparative investigation of the reduction of NO by CH4 on Pt, Pd, and Rh catalysts[J].Applied Catalysis,1998,B15:49-62. |
[5] | Philippe O.Thevenin;Ana Alcalde;Lars J.Pettersson;Sven G.Jaras;Jose Luis G.Fierro .Catalytic combustion of methane over cerium-doped palladium catalysts[J].Journal of Catalysis,2003(1):78-86. |
[6] | Yun-feng chang;Jon G McCarty .Novel oxygen storage components for advanced catalysts for emission control in natural gas fueled vehicles[J].Catalysis Today,1996,30:163-170. |
[7] | Yasushi Ozawa;Yoshihisa Tochihara .PdO/Al2O3 in catalytic combustion of methane: stabilization and deactivation[J].Chemical Engineering Science,2003,58:671-667. |
上一张
下一张
上一张
下一张
计量
- 下载量()
- 访问量()
文章评分
- 您的评分:
-
10%
-
20%
-
30%
-
40%
-
50%