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研究了用聚丙烯酰胺作光敏剂的纳米Ag粒子的光化学合成.结果表明,Ag+-PAM-PVP乙醇水溶液中,PAM明显地加速了光化学反应.讨论了PAM作光敏剂的光还原反应机理.在选择的体系中实验了各种组分的影响.在有或无丙酮存在下,TEM表征获得的胶体银粒子,平均直径分别为10.2nm和32.1nm,二者均具有良好的分散性.

参考文献

[1] Taleb A;Petit C;Pileni M P .Optical properties of self-assembled 2D and 3D superlattices of silver nanoparticles[J].Journal of Physical Chemistry B,1998,10:2214-2220.
[2] Schmid G .Large clusters and colloids:metals in the embryonic state[J].Chemical Reviews,1992,92:1709-1727.
[3] Jiang XC.;Lu J.;Zhu LY.;He W.;Qian YT.;Xie Y. .Preparation, characterization, and catalytic effect of CS2-stabilized silver nanoparticles in aqueous solution[J].Langmuir: The ACS Journal of Surfaces and Colloids,2001(13):3795-3799.
[4] Sun Y G;Xia Y N .Shape-controlled synthesis of gold and silver nanoparticles[J].Science,2002,298:2176-2179.
[5] Yu WY.;Liu HF. .Quantity synthesis of nanosized metal clusters[J].Chemistry of Materials,1998(5):1205-1207.
[6] 汪国忠,张伟,崔峙.纳米级Ag粉的制备[J].合成化学,1998(03):226-228.
[7] Abhijit M;Toyoko I;Keigo A et al.Synthesis of dendrimer-passivated noble metal nanoparticles in a polamedium: comparison of size between silver and gold particles[J].CHEMISTRY OF MATERIALS,2001,13:1674-1681.
[8] 彭子飞;张立德 .尺寸可控纳米级银的制备方法[P].CN:1128188
[9] Huang H H;Ni X P;Loy G L et al.Photochemical formation of silver nanoparticles in poly(n-vinylpyrrolidone)[J].Langmuir,1996,12(04):909-912.
[10] 钟福新,蒋治良,李芳,李廷盛,梁宏.纳米银胶的光化学制备及其共振散射光谱研究[J].光谱学与光谱分析,2000(05):724-726.
[11] Itakura T;Torigoe K;Esumi K .Preparation and characterization of ultrafine metal particle in ethanol by irradiation using a photoinitiator[J].Langmuir,1995,11:4129-4134.
[12] Tomoo S;Hiromichi O;Yoshiro Y et al.Sensitized photoreduction of silver ions in the presence oacetophenone[J].Journal of Photochemistry and Photobiology A:Chemistry,1999,127:83-87.
[13] Rabilloud T;Vuillard L;Gilly C et al.Silver-staining of proteins in polyacrylamide gels: a general overview[J].Cellular and Molecular Biology,1994,40(01):57-75.
[14] Yonezawa Y;Sato T;Kuroda S .Photochemical Formation of Colloidal Silver: Peptizing Action of Acetone Ketyl Radical[J].Journal of the Chemical Society,Faraday Transactions,1991,87:1905-1910.
[15] Henglein A. .Colloidal silver nanoparticles: Photochemical preparation and interaction with O-2, CCl4, and some metal ions[J].Chemistry of Materials,1998(1):444-450.
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