实验对比了熔剂中硫和镍的质量(mS和mNiO)变化对镍扣质量(mbutton)的影响,结果表明:mbutton主要受mNiO的控制,mS的变化对其影响则较小.采用X射线衍射(XRD)分析了6个不同mS、mNiO的熔剂所制备镍扣的矿物成分,结果显示:镍扣矿物成分单一,以Ni3S2为主,含少量NixS6,不含NiS、Ni3S4和NiS2等矿物.改变所加入的mS和mNiO,镍扣的矿物组成并不改变,仅是Ni3S2和NixS6相对含量发生变化.
In order to understand the influence of changing contents of nickel and sulfur on the constituents of nickel sulfide button, six buttons of different collector charge were studied. The components were further confirmed by X-ray diffraction (XRD).The experimental results show that, the weight of the of button is mainly controlled by the content of nickel, the button contains mostly Ni3S2, and some NixS6 without any minerals of NiS, Ni3S4 or NiS2. The mineral variety does not change with different contents of nickel and sulfur, only the relative percentage of Ni3S2 and NixS6 alters.
参考文献
[1] | Wolfgang D. Maier;Sarah-Jane Barnes;Julian S. Marsh .The concentrations of the noble metals in Southern African flood-type basalts and MORB: implications for petrogenesis and magmatic sulphide exploration[J].Contributions to Mineralogy and Petrology,2003(1):44-61. |
[2] | J. Pasava;A. Vymazalova;S. Petersen .PGE distribution in massive sulfides from the PACMANUS hydrothermal field, eastern Manus basin, Papua New Guinea: implications for PGE enrichment in some ancient volcanogenic massive sulfide deposits[J].Mineralium deposita,2004(7):784-792. |
[3] | Snow J E;Schmidt G .Constraints on earth accretion deduced from noble metals in the oceanic mantle[J].Nature,1998,391(08):166-169. |
[4] | Bockrath C;Ballhaus C;Holzheid A .Fractionation of the platinum-group elements during mantle melting[J].Science,2004(5692):1951-1953. |
[5] | Luguet A.;Lorand JP.;Seyler M. .Sulfide petrology and highly siderophile element geochemistry of abyssal peridotites: A coupled study of samples from the Kane Fracture Zone (45 degrees W 23 degrees 20N, MARK Area, Atlantic Ocean)[J].Geochimica et Cosmochimica Acta: Journal of the Geochemical Society and the Meteoritical Society,2003(8):1553-1570. |
[6] | Robért RVD;van Wyk E;Palmer R .Concentration of the noble metals by a fire-assay technique using nickel sulphide as the collector[National Institute of Metallurgy,South Africa,Rep No.1371][R].,1971. |
[7] | X. L. Li;M. Ebihara .Determination of all platinum-group elements in mantle-derived xenoliths by neutron activation analysis with NiS fire-assay preconcentration[J].Journal of Radioanalytical and Nuclear Chemistry: An International Journal Dealing with All Aspects and Applications of Nuclear Chemistry,2003(1):131-135. |
[8] | Gros M.;Lorand JP.;Luguet A. .Analysis of platinum group elements and gold in geological materials using NiS fire assay and Te coprecipitation; the NiS dissolution step revisited[J].Chemical geology,2002(3-4):179-190. |
[9] | R. Juvonen;T. Lakomaa;L. Soikkeli .Determination of gold and the platinum group elements in geological samples by ICP-MS after nickel sulphide fire assay: difficulties encountered with different types of geological samples[J].Talanta: The International Journal of Pure and Applied Analytical Chemistry,2002(3):595-603. |
[10] | Paukert T;Rube?ka I .Effects of fusion charge composition on the determination of platinum group elements using collection into a minimized nickel sulphide button[J].Analytica Chimica Acta,1993,278(01):125-136. |
[11] | 刘小荣,董守安.铂族元素和金的硫化镍试金预富集在现代仪器分析方法中的应用[J].贵金属,2002(01):45-52. |
- 下载量()
- 访问量()
- 您的评分:
-
10%
-
20%
-
30%
-
40%
-
50%