通过硝酸和高温2种不同方法处理活性炭与未处理的活性炭进行比较.以红外光谱,氮气吸附脱附测定活性炭表面基团、比表面、孔径孔容的变化.以XRD、TPR、SEM对3种不同催化剂进行表征,并通过对氯硝基苯加氢制对氯苯胺来检测催化剂的活性.结果表明,高温处理活性炭后其比表面和孔容略有升高,表面基团发生了改变,催化剂活性提高.
参考文献
[1] | Auer E;Freund A;Pietsch J.Carbons as supports forindustrial precious metal catalysts[J].Applied Catalysis A:General,1998(173):259-271. |
[2] | Tang Qinghu;Huang Xiaona .Characterization and catalytic application of highly dispo-rsed manganeseoxides supported on activated carbon[J].Journal of Molecular Catalysis A:Chemical,2009,301(1/2):24-30. |
[3] | Guido Protzmann;Gerhard Luft .A new immobilized Rh (I)-carbonylation catalyst[J].Applied Catalysis A:General,1998,172(01):159-163. |
[4] | 熊晓东,王胜国,梁敬博,李茂良,张曦.铑在均相催化工业中的应用[J].稀有金属,2005(04):403-407. |
[5] | 吴廷华;汪海有;翁维正 等.甲烷部分氧化制合成气[J].催化学报,1998,19(06):498-502. |
[6] | 熊伟,刘德蓉.负载型铑催化剂催化苯乙酮的多相不对称氢化反应的研究[J].西昌师范高等专科学校学报,2004(04):35-37. |
[7] | Hisashi Tamai;Nobuaki .Preparation of Pd supported mesoporous activated carbons and their catalytic activity[J].Materials Chemistry and Physics,2009,114:10-13. |
[8] | Okhlopkova L B;Lisitsyn A S;Likholobov V A et al.Properties of Pt/C and Pd/C catalysts prepared by reduction with hydrogen of adsorbed metal chlorides:Influence of pore structure of the support[J].Applied Catalysis A:General,2000,204(02):229-234. |
[9] | Li L;Zhu ZH;Lu GQ;Yan ZF;De Marco R .Synthesis and characterization of turbostratic carbons prepared by catalytic chemical vapour decomposition of acetylene[J].Applied Catalysis, A. General: An International Journal Devoted to Catalytic Science and Its Applications,2006(2):201-209. |
[10] | Coloma F;Prado-Burguete C;Rodriguez-Reinoso F .Pt-C interaction in catalyst supported on a carbon black subjected to different heat treatments[J].Studies in Surface Science and Catalysis,1993,75(03):2103-2106. |
[11] | Min Kang;Youn-Sang Bae;Chang-Ha Lee .Effect of heat treatment of activated carbon supports on the loading and activity of Pt catalyst[J].Carbon: An International Journal Sponsored by the American Carbon Society,2005(7):1512-1516. |
[12] | Marjolein L.Toebes;Jos A.van Dillen;Krijn P.de Jong .Synthesis of supported palladium catalysts[J].Journal of molecular catalysis, A. Chemical,2001(1/2):75-98. |
[13] | Rodriguez-Reinoso F. .The role of carbon materials in heterogeneous catalysis[J].Carbon: An International Journal Sponsored by the American Carbon Society,1998(3):159-175. |
[14] | Cameron D S;Cooper S J;Dodgson L L et al.Carbons as supports for precious metal catalysts[J].Catalysis Today,1990,7(02):113-137. |
[15] | 陈晨,林性贻,于政锡,陈晓晖,郑起,魏可镁.硝酸处理活性炭对醋酸乙烯催化活性的影响[J].石油化工,2004(11):1024-1027. |
[16] | 刘广臻,郑晓玲,许交兴,魏可镁.活性炭载体预处理对Ru/C氨合成催化剂活性的影响[J].工业催化,2004(06):44-47. |
[17] | 郑晓玲,傅武俊,俞裕斌,林建新,魏可镁.活性炭载体的微波处理对氨合成催化剂Ru/C催化性能的影响[J].催化学报,2002(06):562-566. |
[18] | 贾荣利,王成扬,王素梅.炭载体前处理对Pt/C催化剂Pt分散性的影响[J].电源技术,2005(12):801-804. |
[19] | 邱介山;王艳斌;邓贻钊 .几种活性炭表面酸性基团的测定及其对吸附性能的影响[J].炭素技术,1996,4:11-17. |
[20] | Teresa J Bandosz;Jacek Jagiello;James A Schwarz .Comparison of methods to assess surface acidic groups on activated carbons[J].Analytical Chemistry,1992,64:891-895. |
[21] | Usmani TH.;Ahmed SZ.;Yousufzai AHK.;Ahmed TW. .PREPARATION AND CHARACTERIZATION OF ACTIVATED CARBON FROM A LOW RANK COAL[J].Carbon: An International Journal Sponsored by the American Carbon Society,1996(1):77-82. |
[22] | 邹勇;郭幼庭 .高吸附性能木素活性炭表面含氧基团的研究[J].北京林业大学学报(自然科学版),1992,14(04):138-142. |
[23] | 王向宇,梁丽珍,徐三魁,李利民.有机助剂对葡萄糖加氢反应中RU/C催化剂的影响[J].郑州大学学报(理学版),2005(04):80-83. |
[24] | 徐三魁,王向宇,梁丽珍.葡萄糖加氢制山梨醇Ru/C催化剂的活性及TPR研究[J].河南工业大学学报(自然科学版),2006(02):67-69. |
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