介绍了钛基涂层氧化物析氧阳极(DSA)的制备方法,包括热分解、磁控溅射、溶胶-凝胶和电沉积等方法.分析了DSA阳极的析氧原理.指出了DSA电极存在的问题及未来的发展趋势.
参考文献
| [1] | 胡耀红,陈力格.DSA涂层钛阳极及其应用[J].电镀与涂饰,2003(05):58-59. |
| [2] | 张招贤.钛电极工学[M].北京:冶金工业出版社,2003 |
| [3] | N. A. Abdel Ghany;N. Kumagai;S. Meguro;K. Asami;K. Hashimoto .Oxygen evolution anodes composed of anodically deposited Mn-Mo-Fe oxides for seawater electrolysis[J].Electrochimica Acta,2002(1):21-28. |
| [4] | TRASATTI S .Electrocatalysis in the anodic evolution of oxygen and chlorine[J].Electrochimica Acta,1984,29(11):1503-1512. |
| [5] | 董睿,李伟善.多色钛阳极氧化膜的耐蚀性研究[J].电镀与涂饰,1999(01):17-20. |
| [6] | Mario H. P. Santana;Luiz A. De Faria .Oxygen and chlorine evolution on RuO{sub}2 + TiO{sub}2 + CeO{sub}2 + Nb{sub}2O{sub}5 mixed oxide electrodes[J].Electrochimica Acta,2006(17):3578-3585. |
| [7] | CASTRO E B;GERVASI C A .Electrodeposited Ni-Co-oxide electrodes:characterization and kinetics of the oxygen evolution reaction[J].International Journal of Hydrogen Energy,2000,25(12):1163-1170. |
| [8] | Slavko V. Mentus .Oxygen reduction on anodically formed titanium dioxide[J].Electrochimica Acta,2004(1):27-32. |
| [9] | BEARD B C;ROSS P N JR .Characterization of a titanium-promoted supported platinum electrocatalyst[J].Journal of the Electrochemical Society,1986,133(09):1839-1845. |
| [10] | NEOPHYTIDES S G;ZAFEIRATOS S H;JAKSIC M M .Selectire interactive grafting of composite bifunctional electrocatalysts for simultaneous anodic hydrogen and CO oxidation[J].Journal of the Electrochemical Society,2003,150(10):E512-E526. |
| [11] | SHIM J;LEE C R;LEE H k et al.Electrochemical characteristics of Pt-WO3/C and Pt-TiO2/C electrocatalysts in a polymer electrolyte fuel cell[J].Journal of Power Sources,2001,102(1-2):172-177. |
| [12] | HARUTA M;TSUBOTA S;KOBAYASHI T et al.Low-temperature oxidation of CO over gold supposed on TiO2,α-Fe2O3,and CO3O4[J].Journal of Catalysis,1993,144(01):175-192. |
| [13] | Okumura M.;Ueda A.;Haruta M.;Tanaka K. .THE REACTIVITIES OF DIMETHYLGOLD(III)BETA-DIKETONE ON THE SURFACE OF TIO2 - A NOVEL PREPARATION METHOD FOR AU CATALYSTS[J].Solid state ionics,1997(1/2):143-149. |
| [14] | 谭琛,苏艳舟.酸性介质中长效析氧阳极的研究[J].氯碱工业,2005(02):21-23. |
| [15] | G. Foti;C. Mousty;V. Reid;Ch. Comninellis .Characterization of DSA type electrodes prepared by rapid thermal decomposition of the metal precursor[J].Electrochimica Acta,1998(5):813-818. |
| [16] | C. Mousty;G. Foti;Ch. Comninellis;V. Reid .Electrochemical behaviour of DSA type electrodes prepared by induction heating[J].Electrochimica Acta,1999(3):451-456. |
| [17] | PELEGRlNO R R L;VICENTIN L C;DE ANDRADE A R et al.Thirty minutes laser calcination method for the preparation of DSA(R) type oxide electrodes[J].Electrochemistry Communications,2002,4(02):139-142. |
| [18] | 潘建跃,孙凤梅,罗启富.钛阳极磁控溅射钽的工艺研究[J].材料保护,2004(10):26-28. |
| [19] | 陶自春,潘建跃,罗启富.铂中间层的制备及对铱钽涂层钛阳极性能的影响[J].材料科学与工程学报,2004(02):240-244. |
| [20] | Panic VV;Dekanski AB;Milonjic SK;Miskovic-Stankovic VB;Nikolic BZ .Electrocatalytic activity of sol-gel-prepared RuO2/Ti anode in chlorine and oxygen evolution reactions[J].Russian journal of electrochemistry,2006(10):1055-1060. |
| [21] | 唐电,文仕学,陈士仁.RuO260%-TiO240%纳米材料的制备与表征[J].金属热处理学报,2000(03):12-16. |
| [22] | Juliane Cristina Forti;Paulo Olivi;Adalgisa R. de Andrade .Characterization of DSA-type coatings with nominal composition Ti/Ru{sub}0.3Ti{sub}(0.7-x)Sn{sub}xO{sub}2 prepared via a polymeric precursor[J].Electrochimica Acta,2001(6):913-920. |
| [23] | FUJIMURA K;MATSUI T;IZUMIYA K et al.Oxygen evolution on manganese-molybdenum oxide anodes in seawater electrolysis[J].Materials Science and Engineering,1999,267A(02):254-259. |
| [24] | 王鹏,姚立广,王明贤,吴维(X).碱性水电解阳极材料研究进展[J].化学进展,1999(03):254-264. |
| [25] | TSEUNG A C C;JASEM S .Oxygen evolution on semiconducting oxides[J].Electrochimica Acta,1977,22(01):31-34. |
| [26] | VITHANAGE R;FINKLEA H O .The stability of silane layers on titanium dioxide electrodes[J].Journal of the Electrochemical Society,1984,131(04):799-803. |
| [27] | S.Nijjer;J.Thonstad;G.M.Haarberg .Cyclic and linear voltammetry on Ti/IrO_2-Ta_2O_5-MnO_x electrodes in sulfuric acid containing Mn~(2+) ions[J].Electrochimica Acta,2001(23):3503-3508. |
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