纳米氧化锌是一种广泛应用于橡胶、日用化工、涂料、电子等工业领域的重要的功能材料.对固相法、液相法、气相法制备纳米氧化锌的基本原理、影响因素、产物粒径大小等进行了详细的分析讨论,同时提出了每种工艺的优缺点,以及最适当的工艺条件.分析表明,目前生产纳米氧化锌的方法大多为液相沉淀法,但沉淀中存在阴离子洗涤和去除问题,难以完全解决.而气相法成本较高,难以实现大规模生产.固相法无需溶剂、产率高、反应条件易掌握,可望实现工业化生产.作者认为未来的研究主要应该集中于去除杂质,降低生产成本,开发绿色新工艺及其纳米氧化锌应用领域等方面.
参考文献
| [1] | 和田伸彦 .[J].日本的科学与技术,1985,1:1. |
| [2] | 都有为.超微颗粒的物理特性[J].材料导报,1992(05):1. |
| [3] | Parker D W et al.[J].Current Advances in Materials and Processes,1991,139:68. |
| [4] | Shingu P H .[J].Suppl Trans Japan Inst Metals,1988,3:29. |
| [5] | Mikrajuddin.;Okuyama K.;Shi FG.;Iskandar F. .Stable photoluminescence of zinc oxide quantum dots in silica nanoparticles matrix prepared by the combined sol-gel and spray drying method[J].Journal of Applied Physics,2001(11 Pt.1):6431-6434. |
| [6] | Matsuoka M .Nonohmic properties of ZnO oxide ceramics[J].Japanese Journal of Applied Physics,1971,10(06):736. |
| [7] | Levinson L M;Philip H R .Zinc oxide varistors-A review[J].American Ceramic Society Bulletin,1986,65(04):639. |
| [8] | Cerva H;Russwurm W .Microstructure and crystal structure of bismuth oxide phases in zinc oxide varistor ceramics[J].American Ceramic Society Bulletin,1986,65:639. |
| [9] | Greuter F;Blatter G .Electrical properties of grain boundaries in polycrystalline compound semiconductors[J].Semiconductor Science and Technology,1990,5:111. |
| [10] | Levinson L M;Philipp H R .[J].American Ceramic Society Bulletin,1996,56:539. |
| [11] | 陈建勋;赵端荣;蒋汉瀛 .氧化锌压敏陶瓷及其粉体的制备现状与展望[J].陶瓷工程,1997,31(02):33. |
| [12] | Einzinger R .Metal oxide varistors[J].Annual Review of Materials Science,1987,17:299. |
| [13] | Levivine J O .Theory of varistor electronic properties[J].Critical Review in Solid State and Materials Sciences,1975,5:597. |
| [14] | Morris W G .Physical properties of electrical barries in varistor[J].Journal of Vacuum Science and Technology,1976,13:926. |
| [15] | Bernasconi J;Strassler S;knecht B et al.Zinc oxide varistor:a possible mechanism[J].Solid State communications,1977,21:867. |
| [16] | 黄波.固体材料及其应用[M].广州:华南理工大学出版社,1995 |
| [17] | 大连化学物理研究所 .[P].CN 1062345,1992. |
| [18] | 郁平,房鼎业.纳米氧化锌的制备[J].化学世界,2000(06):293. |
| [19] | 靳建华,白炳贤,白涛,徐新生.氨水沉淀法制备纳米粉氢氧化锌和氧化锌[J].无机盐工业,2000(06):7-8. |
| [20] | 卫志贤;雷闫盈;李晓娥 等.纳米氧化锌中试研究[J].无机盐工业,1999,31(05):8. |
| [21] | HohenBergerG;Tomamdl G .[J].Journal of Materials Research,1992,7(03):546. |
| [22] | 刘素琴,黄可龙,宋志方,彭斌.Sol-Gel法制备 ZnO压敏陶瓷及其电性[J].无机材料学报,2000(02):376-380. |
| [23] | 董远达 等.溶胶-凝胶工艺和氧化物气敏材料[J].功能材料,1992,23(01):18. |
| [24] | Jezequel D;Guenot J;Jouini N et al.[J].Materials Science Forum,1994,152-153:339. |
| [25] | 朱勇 等.激光加热制备ZnO纳米粉[J].无机材料学报,1993,8(01):111. |
| [26] | 王零森.特种陶瓷[M].长沙:中南大学出版社,1994:59. |
| [27] | Mitarai;Takeshi .[P].JP 63288914 |
| [28] | Seiyama T et al.[J].Analytical Chemistry,1962,34:1505-1503. |
| [29] | 娄向东.ZnO系半导体陶瓷气敏传感器的进展[J].传感器技术,1991(03):1. |
| [30] | 徐甲强 等.ZnO系气敏陶瓷的制备与气敏性能研究[J].功能材料,1993,24(01):30. |
| [31] | 徐甲强 等.半导体气体传感器的选择性研究[J].传感器世界,1997,3(08):7. |
| [32] | Lauf R J;Band W D .[J].Journal of Materials Science,1995,30:2733. |
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