液相共沉积法制备正庚烷基磁性液体,为了研究油酸对纳米粒子的包覆作用,采用红外光谱分别测试Fe3O4纳米粒子、油酸及正庚烷基铁氧体磁性液体.比较其结果得出,油酸通过端羧基与Fe3O4纳米粒子之间的化学反应来实现对其表面包覆,包覆过程没有破坏油酸的非极性链,确保包覆后的油酸具有与非极性载液相容性,此为磁性液体表面活性剂的本质作用.
参考文献
[1] | 周继斌;陆永平.磁性流体密封原理与设计[M].北京:国防工业出版社,2000:22-23. |
[2] | 余宗宝;李国斌 .高性能磁性液体材料研究进展[J].功能材料,2007,38(zk):1179-1181. |
[3] | 陈英方.红外和喇曼光谱技术[M].北京:纺织工业出版社,1988:2. |
[4] | Chia-Lung Lin;Chia-Fen Lee;Wen-Yen Chiu .Preparation and properties of poly(acrylic acid)oligomer stabilized superparamagnetic ferrofluid[J].Journal of Colloid and Interface Science,2005(2):411-420. |
[5] | Bourlinos A B;Bakandritsos A;Georgakilas V.Facile synthesis of capped γ-Fe2O3 and Fe3O4nanoparticles[J].Journal of Materials Science |
[6] | Sartoratto P P C;Neto A V S;Lima E C D.Preparation and electric properties of oil-based magnetic fluids[J].Journal of Applied Physics,2005(97):1-3(10Q917). |
[7] | Hong RY;Zhang SZ;Han YP;Li HZ;Ding J;Zheng Y .Preparation, characterization and application of bilayer surfactant-stabilized ferrofluids[J].Powder Technology: An International Journal on the Science and Technology of Wet and Dry Particulate Systems,2006(1):1-11. |
[8] | Rafael Tadmor;Ronald E Rosensweig;Joseph Frey et al.Resolring the puzzle of ferrofluid dispersants[J].Langmuir,2000,16:9117-9120. |
[9] | 沈钟;王果庭.胶体与表面化学[M].北京:化学工业出版社,1997:163-164. |
上一张
下一张
上一张
下一张
计量
- 下载量()
- 访问量()
文章评分
- 您的评分:
-
10%
-
20%
-
30%
-
40%
-
50%