表面涂层技术和基体改性是对碳/碳复合材料进行氧化防护的主要措施.对近年来碳/碳复合材料基体抗氧化改性传统技术方法进行全面总结,主要有碳纤维改性、液相浸渍法、添加剂法、催化杂质的直接脱除或失活、基体置换法.介绍碳/碳复合材料基体抗氧化改性新工艺,提出并设计3种碳/碳复合材料基体抗氧化改性最新工艺.并对碳/碳复合材料基体改性研究的发展趋势进行了展望.
Many investigations have shown that surface coating technology and matrix modification for carbon/carbon(C/C)composites are the principal methods used for anti-oxidation protection.In this paper,current research on the traditional methods of matrix anti-oxidation modification for C/C composites is summaried,including carbon fiber modification,liquid-phase impregnation,additives,the removal or inactivation of the catalytic impurities and matrix displacement method.New technologies for matrix modification are introduced and three novel strategies are designed for the improvement of the oxidation resistance of C/C composites.And the direction of matrix modification for C/C composites is proposed.
参考文献
[1] | Sheehan J E;Buesking K W;Sullivan B J .Carbon-carbon composites[J].Materials Science,1994,24(01):19-44. |
[2] | Westwood ME.;Day RJ.;Hayes FH.;Taylor R.;Webster JD. .OXIDATION PROTECTION FOR CARBON FIBRE COMPOSITES [Review][J].Journal of Materials Science,1996(6):1389-1397. |
[3] | 黄剑锋,李贺军,熊信柏,曾燮榕,李克智,付业伟,黄敏.炭/炭复合材料高温抗氧化涂层的研究进展[J].新型炭材料,2005(04):373-379. |
[4] | Lobiondo NE.;Clare AG.;Jones LE. .HALOGENATED GLASS SYSTEMS FOR THE PROTECTION OF STRUCTURAL CARBON-CARBON COMPOSITES[J].Carbon: An International Journal Sponsored by the American Carbon Society,1995(4):499-508. |
[5] | Weiming Guo;Banning Xiao;Eiichi Yasuda .Oxidation kinetics and mechanisms of a 2D-C/C composite[J].Carbon: An International Journal Sponsored by the American Carbon Society,2006(15):3269-3276. |
[6] | 曾志安,崔红,李瑞珍.C/C复合材料高温抗氧化研究进展[J].炭素,2006(01):12-16. |
[7] | Teddy M.Keller .Oxidative protection of carbon fibers with poly(carborane-siloxane-acetylene)[J].Carbon: An International Journal Sponsored by the American Carbon Society,2002(3):225-229. |
[8] | Suzuki Y;Inoue Y;lzawa J et al.Microstructural change of pitch derived carbon matrix in C/C composite by zone treatment on carbon fiber[J].CARBON,1996,34(05):689. |
[9] | Jin Z;Zhang ZQ;Meng LH .Effects of ozone method treating carbon fibers on mechanical properties of carbon/carbon composites[J].Materials Chemistry and Physics,2006(1):167-172. |
[10] | Zayat M;Davidov D;Selig H et al.Fluorination of carbon fibers by halogen fluorides[J].CARBON,1994,32(03):485-491. |
[11] | Ho C T;Chung D D L .Inhibition of the oxidation of carboncarbon composites by bromination[J].Carbon,1990,28(06):815-824. |
[12] | Sogabe T.;Kuroda K.;Inagaki M.;Okada O. .IMPROVEMENT IN PROPERTIES AND AIR OXIDATION RESISTANCE OF CARBON MATERIALS BY BORON OXIDE IMPREGNATION[J].Carbon: An International Journal Sponsored by the American Carbon Society,1997(1):67-72. |
[13] | Weiming Lu;D.D.L.Chung .Oxidation protection of carbon materials by acid phosphate impregnation[J].Carbon: An International Journal Sponsored by the American Carbon Society,2002(8):1249-1254. |
[14] | 刘重德,邵泽钦,陆玉峻.抗氧化浸渍炭-石墨材料的研究及性能分析[J].炭素技术,2000(01):15-17. |
[15] | 易茂中,葛毅成,彭春兰,黄伯云.预浸涂对航空刹车副用C/C复合材料抗氧化涂层性能的影响[J].中国有色金属学报,2002(02):260-263. |
[16] | McKee D W .Borate treatment of carbon fibers and carbon/carbon composites for improved oxidation resistance[J].Carbon,1986,24(06):737-741. |
[17] | Steiribruck M .Oxidation of boron carbide at high temperatures[J].Journal of Nuclear Materials: Materials Aspects of Fission and Fusion,2005(2/3):185-193. |
[18] | Li YQ;Qiu T .Oxidation behaviour of boron carbide powder[J].Materials Science & Engineering, A. Structural Materials: Properties, Misrostructure and Processing,2007(1/2):184-191. |
[19] | 刘其城,周声劢,徐协文,周艺.无黏结剂碳/陶复合材料的抗氧化机理[J].化工学报,2002(11):1188-1192. |
[20] | Zhuangjun Fan;Yongzhong Song;Lang Liu;Jingli Shi .Oxidation behavior of fine-grained SiC-B_4C/C composites up to 1400degC[J].Carbon: An International Journal Sponsored by the American Carbon Society,2003(3):429-436. |
[21] | Dacic B;Marinkovic S .Kinetics of air oxidation of unidirectional carbon fibres/CAD carbon composites[J].Carbon,1987,25(03):409-415. |
[22] | 储双杰.碳/碳复合材料的氧化与防护[J].材料工程,1992(05):43. |
[23] | 王道岭,汤素芳,邓景屹,刘文川.熔融硅液相浸渍法制备C/C-SiC复合材料[J].材料研究学报,2007(02):135-139. |
[24] | Lamouroux F.;Naslain R.;Thebault J.;Bourrat X. .SILICON CARBIDE INFILTRATION OF POROUS C-C COMPOSITES FOR IMPROVING OXIDATION RESISTANCE[J].Carbon: An International Journal Sponsored by the American Carbon Society,1995(4):525-535. |
[25] | 黄剑锋;王妮娜;曹丽云 .一种碳,碳复合材料溶剂热改性方法[P].中国,CN200710018031,2007-12-05. |
[26] | 黄剑锋;李贺军;曹丽云 等.一种微波水热电沉积制备涂层或薄膜的方法及装置[P].中国,CN200510096086,2006-04-26. |
[27] | 王妮娜,黄剑锋,曹丽云,曾燮榕.硅溶胶水热处理及添加B2O3微粉改性碳/碳复合材料的抗氧化性能[J].硅酸盐学报,2008(11):1577-1581. |
[28] | 黄剑锋;李贺军;曹丽云 等.一种超声水热电沉积制备涂层或薄膜的方法及其装置[P].中国,CN200510096087,2006-05-03. |
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