无机纳米杂化聚酰亚胺(PI)薄膜具有优良的耐电晕特性,通过观察击穿孔区形貌研究薄膜击穿机理及纳米颗粒的作用,利用SEM观察阶梯式升压强电场击穿无机纳米杂化PI薄膜孔区形貌,能谱仪测试孔区附近元素分布.研究表明:杂化薄膜严重破坏区域仅局限在孔洞附近10~50 μm范围内,随半径增加,其表面由颗粒大小不均匀、表面粗糙不平,逐渐过渡到颗粒均匀的微观结构状态;Cu含量逐渐减少,Au含量逐渐增加,正常区域电极表面没有损伤;氧化铝纳米颗粒在杂化薄膜中起到阻止电极破坏的作用,薄膜击穿机理属热击穿类型.
参考文献
[1] | BLAISE G;GRESSUS C L .Charging and flashover induced by surface polarization relaxation process[J].Journal of Applied Physics,1991,69:6334-6339. |
[2] | 张明艳,王芳,金镇镐,衷敬和,曾恕金,范勇,雷清泉.无机组分对聚酰亚胺杂化薄膜电性能的影响[J].材料科学与工艺,2004(06):576-578,582. |
[3] | Le Gressus C.;Blaise G. .Breakdown phenomena related to trapping/detrapping processes in wide band gap insulators[J].IEEE transactions on electrical insulation. (Institute of Electrical and Electronics Engineers. Electrical Insulation Group). New York.,1992(3):472-481. |
[4] | Teyssedre G.;Montanari GC.;Palmieri F.;See A.;Dissado LA. Fothergill JC.;Laurent C. .Charge distribution and electroluminescence in cross-linked polyethylene under dc field[J].Journal of Physics, D. Applied Physics: A Europhysics Journal,2001(18):2830-2844. |
[5] | KIMMEL G A;ORLANDO T M .Observation of negative ion resonances in amorphous ice via low-energy (5 ~ 40eV) electron-stimulated production of molecular hydrogen[J].Physical Review Letters,1996,77:3983-3986. |
[6] | AUGE J L;LAURENT C;FABIANI D et al.Investigating dc polyethylene threshold by space charge.Current and electroluminescencemeasurements[J].IEEE Transactions on Dielectrics and Electrical Insulation,1997,7:797-803. |
[7] | MARY D;ALBERTIN M;LAURENT C .Understanding optical emissions from electrically stressed insulating polymers:electroluminescence in poly (ethylene terephthalate) and poly(ethylene 2,6-naphthalate) films[J].Journal of Physics D:Applied Physics,1997,30:171-184. |
[8] | Hao Cui;Peter A. Burke .Time-dependent dielectric breakdown of hydrogenated silicon carbon nitride thin films under the influence of copper ions[J].Applied physics letters,2004(14):2629-2631. |
[9] | HORVATH J;BIRRINGER R;GLEITER H .Diffusion in nanocrystalline material[J].Journal of Solid State Communications,1987,62:319-322. |
[10] | HIKITA M;ISHINO I;SAWA G et al.Electrical breakdown of linear low-density polyethylene[J].Japanese Journal of Applied Physics,1986,25:500-501. |
[11] | MIZUTANI T;KANNO I;HIKITA M et al.Prebreakdown currents due to filamentary thermal breakdown in polyimide films[J].IEEE Transactions on Electrical Insulation,1987,22:473-477. |
上一张
下一张
上一张
下一张
计量
- 下载量()
- 访问量()
文章评分
- 您的评分:
-
10%
-
20%
-
30%
-
40%
-
50%