钛铁矿在自然界中储量非常丰富,分布较广.本文结合笔者的研究工作,概述和分析了以天然钛铁矿为主要原料,碳热、铝热、镁热等原位合成金属陶瓷材料的还原反应机理,并预测了工业化应用的前景.充分利用钛铁矿中的钛和铁两种资源,原位合成制备金属陶瓷材料,将成为天然钛铁矿综合开发利用中的一个重要方面.
参考文献
[1] | 潘兆橹.结晶学及矿物学[M].北京:地质出版社,1994 |
[2] | 邓国珠.世界钛资源及其开发利用现状[J].钛工业进展,2002(05):9-12. |
[3] | 曹谏非.钛矿资源及其开发利用[J].化工矿产地质,1996(02):127. |
[4] | 王志,袁章福.中国钛资源综合利用技术现状与新进展[J].化工进展,2004(04):349-352. |
[5] | 杨佳,李奎,汤爱涛,潘复生.钛铁矿资源综合利用现状与发展[J].材料导报,2003(08):44-46. |
[6] | BURDEN S J;HONG J;RUE T W et al.Comparison of hot--isostatically pressed and uniaxially hot--pressed alumina--titanium carbide cutting tools[J].American Ceramic Society Bulletin,1988,67(06):1003-1005. |
[7] | 陈寒元;邹正光;欧俊 等.天然矿物钛铁矿原位碳热还原合成TiC/Fe的热力学分析[J].材料科学与工艺,2001,9(zk):227-229. |
[8] | 邹正光,陈寒元,麦立强.钛铁矿原位碳热还原合成TiC/Fe的热力学过程及合成条件研究[J].无机材料学报,2001(05):903-908. |
[9] | 莫畏.钛冶金[M].北京:冶金工业出版社,1979 |
[10] | RABIN B H;KORTH G E;Williamson R L .Fabrication of titanium carbide--alumina composites by combustion synthesis and subsequent dynamic consolidation[J].Journal of the American Ceramic Society,1990,73(07):2156-2157. |
[11] | ZOU Zheng-guang;CHEN Han-yuan et al.Mechanism,properties and microstructure of titanium carbide--iron metal--ceramic from ilmenite by in--situ carbothermic reduction[J].Materials Science Forum,2003,423-425:287-292. |
[12] | BROWN I W M;OWERS W R .Fabrication,Microstructure and properties of fe--tic ceramic--metal composites[J].Current Applied Physics,2004,4(2-4):171-174. |
[13] | TERRY B S;CHINYAMAKOBVU O.Carbothermic Reduction of Ilmenite and Ruffle as Means of Production of Iron Based Ti (O,C) Metal Matrix Composites[J].Materials Science and Technology,1997(07):842-848. |
[14] | Fusheng Pan;Kui Li;Aitao Tang .Influence of High Energy Ball Milling on the Carbothermic Reduction of Ilmenite[J].Materials Science Forum,2003(0):105-108. |
[15] | GALGALI R K;RAY H S;CHAKRABARTI A K .A Study on Carbothermic Reduction of llmenite Ore in a Plasma Reactor[J].Metallurgical and Materials Transactions B:Process Metallurgy and Materials Processing Science,1998,29:1175. |
[16] | P.V.Ananthapadmanabhan;P.R.Taylor .Titanium carbide-iron composite coatings by reactive plasma spraying of ilmenite[J].Journal of Alloys and Compounds: An Interdisciplinary Journal of Materials Science and Solid-state Chemistry and Physics,1999(1/2):121-125. |
[17] | P.V.Anathapadmanabhan;P.R.Taylor .Synthesis of titanium nitride in a thermal plasma reactor[J].Journal of Alloys and Compounds: An Interdisciplinary Journal of Materials Science and Solid-state Chemistry and Physics,1999(1/2):126-129. |
[18] | 吴一,尹传强,李晓敏,邹正光,周浪.FeTiO3-Al-C系统的反应热力学及Al2O3-TiC/Fe 复合材料的制备[J].硅酸盐学报,2005(09):1173-1178. |
[19] | 傅正义.SHS技术研究进展--纪念SHS技术诞生三十周年[J].复合材料学报,2000(01):5-10. |
[20] | ZOU Zheng-guang;LI Jin-lian;WU Yi .The Study of Serf--propagating High--temperature Synthesis of TiC--Al2O3/Fe from Natural llmenile[J].Key Engineering Materials,2005,280-283:1103-1106. |
[21] | 邹正光;李金莲;陈寒元 .TiC-Al2O3/Fe复相金属陶瓷的性能与结构[J].山东大学学报(工学版),2002,32(zk):76-79. |
[22] | 吴一,尹传强,邹正光,周浪,李晓敏.钛铁矿原位合成金属陶瓷复合材料的研究[J].硅酸盐通报,2005(03):21-24. |
[23] | Welham NJ. .Mechanochemical reaction between ilmenite (FeTiO3) and aluminium[J].Journal of Alloys and Compounds: An Interdisciplinary Journal of Materials Science and Solid-state Chemistry and Physics,1998(1/2):228-236. |
[24] | WILLIS P E;KERR A .Ambient Temperature Formation of an Alumina--Titanium Carbide--Metal Ceramic[J].Journal of the European Ceramic Society,1998,18(06):701-708. |
[25] | Welham NJ. .Mechanically induced reduction of ilmenite (FeTiO3) and rutile (TiO2) by magnesium[J].Journal of Alloys and Compounds: An Interdisciplinary Journal of Materials Science and Solid-state Chemistry and Physics,1998(1/2):260-265. |
[26] | 林立.燃烧还原化合法制备氮化钛粉末(Ⅰ)--理论分析[J].材料开发与应用,2000(05):1-5. |
[27] | N.J.Welham;D.J.Llewellyn .Formation of nanometric hard materials by cold milling[J].Journal of the European Ceramic Society,1999(16):2833-2841. |
[28] | CHEN Y;WILLIAMS J S;NINHAM B .Mechanochemical Reactions of Ilmenite with Different Additives[J].Colloids and Surfaces A:Physicochemical and Engineering Aspects,1997,129-130:61-66. |
[29] | CHAO J T;金心.钛铁矿应用于高炉上的实践[J].国外钢铁,1990(11):15-21. |
上一张
下一张
上一张
下一张
计量
- 下载量()
- 访问量()
文章评分
- 您的评分:
-
10%
-
20%
-
30%
-
40%
-
50%