研究了500~700℃纯Cr在NaCl盐膜及水蒸气作用下的腐蚀行为.结果表明,在单纯空气或O2+H2O混合气氛中,由于表面生成了一层连续致密的Cr2O3保护膜,即使在较高温度(700℃)下其腐蚀增重也较小,表现出良好的抗腐蚀性能.但在NaCl+空气或NaCl+O2+H2O协同作用下,Cr的腐蚀明显加剧,且前者较后者的加速作用显著.在试验温度范围内,温度越高,Cr的腐蚀越严重.根据实验结果,讨论了NaCl加速Cr腐蚀的作用机制.
参考文献
[1] | Hiramatsu N;Uematsu Y;Tanaka T;Kinugasa M .Effect of alloying elements on NaCl-induced hot corrosion of stainless steels[J].Materials Science and Engineering,1989,A120:319. |
[2] | Decrescente M A;Bornstein N S .Formation and reactivity thermodynamic of sodium sulfate with gas turbine alloys[J].Corrosion,1968,24:127-133. |
[3] | Shinata Y;Nishi Y .NaCl-induced accelerated oxidation of chromium[J].Oxidation of Metals,1986,26:201-212. |
[4] | 谢俊泉;宋士晖 .镍铬低合金钢在水蒸汽下的氧化动力学[J].北京科技大学学报,1996,18:518-521. |
[5] | Shen J N;Zhou L J;Li T F .High-temperature oxidation of Fe-Cr alloys in wet oxygen[J].Oxidation of Metals,1997,48:347-356. |
[6] | Evans H E;Hilton D A;Holm R A;Simpson P W G .The oxidation of a stainless steel with limited quantities of sea salt[J].Oxidation of Metals,1981,16:327-338. |
[7] | Onay B;Morimoto T;Nakamura S .Corrosion behavior of some Fe-Based alloys in H2-H2O and H2-H2O-HCl gas mixtures at 973K[J].Materials Science Forum,1997,251:591-598. |
[8] | Spiegel M;Schroer C;Grabke H .Corrosion of high alloy steels and Fe-Cr alloys beneath deposits from waste incinerator plants[J].Materials Science Forum,1997,251:527-534. |
[9] | Bakker W T .The effect of chlorine on mixed oxidation/sulfidation of stainless steel below 600℃[J].Materials Science Forum,1997,251:575-582. |
[10] | Saunders S R J;Gohil D D;Banks J P;Sheriff M U Tortorelli P F De Van J H Wright I G .Behavior of FeCr alloy and iron aluminides alloys in coal gasfication atmospheres containing HCl[J].Materials Science Forum,1997,251:583-590. |
[11] | 舒勇华;王福会;周龙江;吴维 .在500-700℃水蒸气和NaCl协同作用下1Cr11Ni2W2MoV钢的腐蚀[J].金属学报,1998,34:483-488. |
[12] | Shu Yonghua;Wang Fuhui;Wu Weitao.Corrosion behavior of Ti60 alloy coated with a solid NaCl deposit in O2 plus water vapor at 500-700℃[J].Oxidation of Metals,1999:52. |
[13] | 舒勇华;王福会;周龙江;吴维 .固态NaCl和水蒸气协同作用下高纯铁的腐蚀行为[J].金属学报,1999,35:311-315. |
[14] | 梁英教;车荫昌.无机物热力学数据手册[M].沈阳:东北大学出版社,1993:8. |
上一张
下一张
上一张
下一张
计量
- 下载量()
- 访问量()
文章评分
- 您的评分:
-
10%
-
20%
-
30%
-
40%
-
50%