获取了不同电位差的钢偶对在海水中以不同面积比偶合的腐蚀结果;讨论了海水中钢偶对的电偶腐蚀行为;对文献中推导的海水中钢偶对的腐蚀速度公式进行了检验和简化.海水中钢偶对阳极的腐蚀速度随阴、阳极自腐蚀电位差和阴/阳极面积比的增大而增大.阳极的腐蚀速度与阴/阳极面积比的关系是非线性的,且阳极的腐蚀速度随阴/阳极面积比的增大有一个极限值.阴极的腐蚀速度随阴/阳极面积比减小和阴/阳极电位差增大而减小.简化的海水中钢偶对的腐蚀速度公式与试验结果符合较好.
Galvanic corrosion results of steel couples with various free corrosion potential difference and surface area ratio of cathode to anode in seawater have been obtained. Galvanic corrosion behavior of the steel couples was discussed. Equation of anodic corrosion rate of steel couples in seawater were examined and simplified. With the increase of free corrosion potential difference and surface area ratio of cathode to anode, the anodic corrosion rates of steel couples increase. The relationship between anodic corrosion rate of steel couples and surface area ratio of cathode to anode is nonlinear. With the increase of surface area ratio of cathode to anode, the anodic corrosion rates have a limit. With the increase of corrosion potential difference between cathode and anode and the decrease of area ratios of cathode to anode, corrosion rate of cathode decreased. The simplified equation of anodic corrosion rate of steel couples in seawater has a good consistence with the experimental results.
参考文献
[1] | 钟积礼.船板钢接触腐蚀的研究[A].北京:科学出版社,1982:32-38. |
[2] | 黎完模;邓淑珍;许绍熙.对907电偶腐蚀行为的研究[A].,1987 |
[3] | 张英;戴明安 .海水中舰船钢低电位差电偶的腐蚀[J].中国腐蚀与防护学报,1993,13(01):87-90. |
[4] | 朱相荣.金属材料的海洋腐蚀与防护[M].北京:国防工业出版社,1999:51-53. |
[5] | 黄桂桥.金属在海水中的腐蚀电位研究[J].腐蚀与防护,2000(01):8-11. |
[6] | 刘大扬;魏开金.金属材料热带海水腐蚀电位序[A].,1994:205-206. |
[7] | 化学工业部化工机械研究院.腐蚀与防护手册-腐蚀理论·试验及监测[M].北京:化学工业出版社,1989:436. |
[8] | Su Fangteng;Charles EA .A theoretical approach to galvanic corrosion allowing cathode dissolution[J].Corrosion Science,1988,28(07):649-655. |
[9] | 黄亚敏;苏方腾 .电化学方法研究12Cr2MoAlRE钢在海水中的耐蚀性[J].中国腐蚀与防护学报,1998,8(01):72-77. |
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