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由微小缝隙模拟管线剥离覆盖层(涂层)下的局部电化学环境,用微电极技术测量了缝隙内局部电位及pH的分布,研究了缝口阴极保护电位、剥离区几何形状、溶液电导率等因素对剥离区内部局部环境及阴极保护水平的影响.结果表明,剥离区内电位降(电位梯度)主要集中在破损口附近,而剥离区深处接近自然腐蚀状态;剥离区内有效保护距离随缝口保护电位负移而增加,但缝口过保护并不能有效提高剥离区保护效果.阴极保护可使剥离区局部电化学环境pH升高、电导率增大.

参考文献

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