研究了不同溶剂对于RTM石英/酚醛复合材料溶液浸润过程的影响.采用X光电子能谱(XPS)和原位电子顺磁共振(EPR)研究了石英纤维表面硅烷偶联剂和不同酚醛树脂溶液组分间的界面化学反应.采用TGA和层间剪切强度(ILSS)测试方法研究了溶剂对酚醛树脂分布和材料界面结合强度的影响.结果表明,溶剂能够与酚醛树脂在石英纤维表面形成竞争性吸附,从而影响树脂在RTM模具内部不同位置的分布和复合材料的力学性能.随着溶剂形成氢键能力的增强,其影响程度依次为四氢呋喃<丙酮<乙醇.
参考文献
[1] | Tohru Morii;Asami Tanaka;Hiroyuki Hamada .Influence of molding condition on tensile properties of flat braided fabric reinforced phenolic composite[J].Composites. Part A, Applied science and manufacturing,2001(10):1505-1511. |
[2] | Averous L.;Gauvin R. .Surface analysis of phenolic composites obtained by RTM process[J].Journal of Reinforced Plastics and Composites,1998(13):1167-1184. |
[3] | RICHARDSON M O W;ZHANG Z Y .Experimental investigation and flow visulisaztion of the resin transfer mould filling process for non-woven hemp reinforced phenolic composites[J].Composites Part A:Applied Science and Manufacturing,2000,31:1303-1310. |
[4] | 路遥,段跃新,梁志勇,张佐光.钡酚醛树脂体系化学流变特性研究[J].复合材料学报,2002(05):33-37. |
[5] | 王继辉,薛理辉,沈大荣.新型酚醛SMC增稠技术及增稠机理的XPS分析[J].武汉工业大学学报,1997(04):91-95. |
[6] | VIVEK P J;ROHINI N K;MOHAN G K et al.Effect of solvents on selectivity in separation using molecularly imprinted adsorptions:separation of phenol and bisphenol A[J].Industrial and Engineering Chemistry,1999,38:4417-4423. |
[7] | MUROSKI A R;NELSON M P;MYRICK M L .Thermodynamic characterization of separation phenomena at the silica/polymer interface within glass-reinforced composites using adsorption chromatography.Part I[J].Journal of Adhesion Science and Technology,1999,13:437-451. |
[8] | SOLOMON J L;MADIX R J;STOEHR J .Orientation and absolute coverage of benzene,aniline,and phenol on Ag(110)determined by NEXAFS and XPS[J].Surface Science,1991,255:12-30. |
[9] | KIVELSON D .Theory of ESR linewidths of free radicals[J].Journal of Chemical Physics,1960,33:1094-1106. |
[10] | KOWALCZYK D;SLOMKOWSKI S .Adsorption of aminopropyltriethoxy silane on quartz:an XPS and contact angle measurements study[J].International Journal of Adhesion and Adhesives,1996,16:227-232. |
[11] | PARMER J F;ZUPANCIC;WISSUCHEK D J .Electron paramagnetic resonance studies of interfacial solvent absorption in quartz fiber-reinforced epoxy composites[J].Composites Part A:Applied Science and Manufacturing,1994,25(07):516-522. |
[12] | REICHARDT C.Solvents and solvent effects in organic chemistry[M].Weinheim:VCH,1988:20-25. |
[13] | EKLUND T;BRITHITCHER L;BBACKMAN J et al.Thermogravimetric analysis of γ-aminopropyl-trimethoxysilane adsorbed on silica support[J].Journal of Thermal Analysis and Calorimetry,1999,58:67-76. |
[14] | SAALBRINK A;LORTEIJE A;PEIJS .The influence of processing parameters on interphase morphology in polymer composites based on phase-separating thermoplast/epoxy blends[J].Composites Part A:Applied Science and Manufacturing,1998,29(9-10):1243-1250. |
上一张
下一张
上一张
下一张
计量
- 下载量()
- 访问量()
文章评分
- 您的评分:
-
10%
-
20%
-
30%
-
40%
-
50%