使用2,3,3',4'-联苯四酸二酐、对苯二胺和反应性封端剂4-苯乙炔苯酐,采用单体原位反应聚合法制备了设计分子量为1500的PMR型聚酰亚胺树脂PEPA-15.PEPA-15树脂溶液具有良好的室温储存稳定性,我们使用AR-2000流变仪对树脂的熔体加工性能进行了初步测试,树脂经过371℃固化后显示了优异的热稳定性,T300碳纤维增强的复合材料经371℃后固化后在动态热机械分析测试(DMA)中在450℃前储能模量没有明显变化.
参考文献
| [1] | Meador MA. .Recent advances in the development of processable high-temperature polymers [Review][J].Annual review of materials research,1998(0):599-630. |
| [2] | Paul M. Hergenrother .The Use, Design, Synthesis, and Properties of High Performance/High Temperature Polymers: an Overview[J].High performance polymers,2003(1):3-45. |
| [3] | 陈祥宝.先进树脂基复合材料的发展[J].航空材料学报,2000(01):46-54. |
| [4] | 谭必恩,益小苏.航空发动机用PMR聚酰亚胺树脂基复合材料[J].航空材料学报,2001(01):55-62. |
| [5] | VANNUCCI R D .PMR polyimide compositions for improved performance at 371℃[J].SAMPE Quarterly,1987,19(01):1-36. |
| [6] | BOWMAN C L;SUTTER J K;THESKEN J C.Characterization of graphite fiber/polyimide composites for RLV applications[A].,2001:1515-1529. |
| [7] | Roger J.Morgan;E.Eugene Shin;Jason Lincoln .Overview of Polymer Matrix Composites Performance and Materials Development for Aerospace Applications[J].SAMPE Journal,2001(2):102-107. |
| [8] | Ronald E.Allred;Sheldon P.Wesson;E.Eugene Shin;Linda Inghram;Linda Mccorkle;Demetrios Papadopoulos;Donald Wheeler;James K.Sutter .The Influence of Sizings on the Durability of High-Temperature Polymer Composites[J].High performance polymers,2003(4):395-419. |
| [9] | MEYER G W;GLASS T E .Synthesis and characterization of polyimides endcapped with phenylethynylphthalic anhydride[J].Journal of Polymer Science Part A:polymer Chemistry,1995,32:2141-2149. |
| [10] | JOHNSTONE J A;LI F M;HARRIS F W .Synthesis and characterization of imide oligomers end-capped with 4-(phenylethynyl)phthalic anhydrides[J].Polymer,1994,35(22):4865-4765. |
| [11] | Kathy C.Chuang;Cheryl L.Bowman;Thomas K.Tsotsis;Cory P.Arendt .6F-Polyimides with Phenylethynyl Endcap for 315-370deg C Applications[J].High performance polymers,2003(4):459-472. |
| [12] | 陈建升,左红军,杨海霞,刘金刚,范琳,杨士勇.适用于RTM成型聚酰亚胺树脂的合成与性能研究[J].航空材料学报,2006(03):183-186. |
| [13] | Hasegawa Masatoshi;Shindo Yoichi;Yokota Rikio;Sensui Nobuyuki .Structure and properties of novel asymmetric biphenyl type polyimides. Homo- and copolymers and blends[J].Macromolecules,1999(2):387-396. |
| [14] | HASEGAWA MASATOSHI;SENSUI NOBUYUKI;SHINDO YOICHI;YOKOTA RIKIO .Improvement of Thermoplasticity for s-BPDA/PDA by Copolymerization and Blend with Novel Asymmetric BPDA-Based Polyimides[J].Journal of Polymer Science, Part A. Polymer Chemistry,1999(17):2499-2511. |
| [15] | TAKAHASHI T;TAKABAYASHI S;INOUE H .Preparation of polyimide films from a-BPDA/ODA by one-pot and two-step imidization methods[J].High Performance Polymers,1998,10(01):33-44. |
| [16] | SERAFINI T T;DELVIGS P;LIGHTSEY G R .Thermally stable polyimides from solutions of monomeric reactants[J].Journal of Applied Polymer Science,1972,16(04):905-915. |
| [17] | HOU T H;JOHNSTON N J;WEISER E S .IM7/LaRCTM-IAX polyimide composites[J].Journal of Advanced Materials,1996,27(04):37-46. |
| [18] | Iroh JO.;Jordan K. .RATE OF IMIDIZATION OF POLYMERIZABLE REACTION MIXTURES - PMR-15[J].Journal of Applied Polymer Science,1997(13):2529-2538. |
| [19] | Fang XM.;Scola DA.;Stevens MP.;Rogers DF. .A study of the thermal cure of a phenylethynyl-terminated imide model compound and a phenylethynyl-terminated imide oligomer (PETI-5)[J].Journal of Polymer Science, Part A. Polymer Chemistry,1998(3):461-470. |
| [20] | Fang XM.;Simone CD.;Stevens MP.;Scola DA.;Xie XQ. .A solid-state C-13 NMR study of the cure of C-13-labeled phenylethynyl end-capped polyimides[J].Macromolecules,2000(5):1671-1681. |
| [21] | Kathy C.Chuang;Cheryl L.Bowman;Thomas K.Tsotsis;Cory P.Arendt .6F-Polyimides with Phenylethynyl Endcap for 315-370deg C Applications[J].High performance polymers,2003(4):459-472. |
上一张
下一张
上一张
下一张
计量
- 下载量()
- 访问量()
文章评分
- 您的评分：
-
10%
-
20%
-
30%
-
40%
-
50%