采用置换原子的热力学模型,计算了Ni-Al-Ta/Mo合金的层错能.分析了Ni-Al-Ta/Mo合金中各元素浓度及温度对层错能的影响.结果表明:Ni-Al-Ta/Mo合金的层错能随Al含量的增加而明显降低,其中,随Al浓度提高,合金中原子偏聚自由能(ΔGγ→εs)降低,可促进γ′有序相的形成是使合金层错能降低的主要原因.随Mo/Ta含量的提高,可引起置换原子自由能(ΔGγ→εb)降低,原子偏聚自由能(ΔGγ→εb)升高;随温度提高,Ni-Al-Ta/Mo合金中的置换原子自由能(ΔGγ→εb)增加,表明合金中发生原子置换需要外部供给能量,而引起原子偏聚自由能(ΔGγ→εs)升高,表明高温不利于溶质原子的偏聚.
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