片状羰基铁具有高的饱和磁化强度和一定的平面各向异性,可突破Snoek限制,在微波吸收领域具有很好的应用前景.本文以球状羰基铁粉为原料,机械球磨制备了片状羰基铁,并根据球磨钢珠配比的改变获得形貌和电磁性能各异的片状羰基铁:随着钢球平均直径的减小,羰基铁片状结构逐渐增多,片状尺寸增大,片层厚度变薄,吸波性能提高;当采用4 mm钢球进行球磨时,片状羰基铁具有最佳吸波性能,其复磁导率的实部和虚部在2 GHz时可达到2.8773和0.9493;涂层厚度为2 mm时,反射率损耗在9.1 GHz处达到最大值-35 dB,小于-10 dB频带宽为7.429 GHz.
参考文献
[1] | 张学良,徐鹏飞,张娇霞,王相.纳米吸波材料的研究进展[J].材料开发与应用,2012(05):75-80. |
[2] | 王雯,王成国,郭宇,陈旸.新型碳基复合吸波材料的制备及性能研究[J].航空材料学报,2012(01):63-67. |
[3] | 陈利民,亓家钟,朱雪琴,葛副鼎.纳米γ-(Fe,Ni)合金颗粒的微观结构及其微波吸收特性[J].兵器材料科学与工程,1999(04):3-6. |
[4] | Xiao-Ling Shi;Mao-Sheng Cao;Jie Yuan;Xiao-Yong Fang .Dual nonlinear dielectric resonance and nesting microwave absorption peaks of hollow cobalt nanochains composites with negative permeability[J].Applied physics letters,2009(16):163108-1-163108-3. |
[5] | CAO M S;WANG R G;FANG X Y .Preparing γ'-Fe N ultrafine powder by twice-nitriding method[J].Powder Technology,2001,115(01):96-98. |
[6] | Wen, FS;Zuo, WL;Yi, HB;Wang, N;Qiao, L;Li, FS .Microwave-absorbing properties of shape-optimized carbonyl iron particles with maximum microwave permeability[J].Physica, B. Condensed Matter,2009(20):3567-3570. |
[7] | Qing YC;Zhou WC;Luo F;Zhu DM .Microwave-absorbing and mechanical properties of carbonyl-iron/epoxy-silicone resin coatings[J].Journal of Magnetism and Magnetic Materials,2009(1):25-28. |
[8] | Qiao L;Wen FS;Wei JQ;Wang JB;Lia FS .Microwave permeability spectra of flake-shaped FeCuNbSiB particle composites[J].Journal of Applied Physics,2008(6):063903-1-063903-5-0. |
[9] | 曹茂盛,高正娟,邹桂真,赵玉娜.超细颗粒/环氧体系电磁参量的计算及数值模拟[J].航空材料学报,2004(03):15-20. |
[10] | 彭智慧,曹茂盛,袁杰,肖钢.雷达吸波材料设计理论与方法研究进展[J].航空材料学报,2003(03):58-63. |
[11] | 葛副鼎;朱静;陈利民 .吸收剂颗粒形状对吸波材料性能的影响[J].宇航材料工艺,1996,5:42-49. |
[12] | Liu Chao;Anjali Sharma;Mohammed N. Afsar;Ogheneyunume Obi;Ziyao Zhou;Nian Sun .Permittivity and Permeability Measurement of Spin-Spray Deposited Ni-Zn-Ferrite Thin Film Sample[J].IEEE Transactions on Magnetics,2012(11):4085-4088. |
[13] | Meng, H.;Zhang, T.;Jiang, C. .Cut-off frequency of magnetostrictive materials based on permeability spectra[J].Journal of Magnetism and Magnetic Materials,2012(12):1933-1937. |
[14] | 秦勇,寇昕莉,薛德胜,李建功.FexCo1-x合金纳米片的微结构与磁性[J].中国有色金属学报,2005(11):1744-1749. |
[15] | 徐丽霞,张世超,刘文博.垂直铜基底钴纳米片阵列的电化学制备及磁性能研究[J].功能材料,2012(05):607-610. |
[16] | 纳米Fe微粒的制备及研究[J].兰州大学学报,1994(01):144. |
[17] | Wenqiang, Z.;Deyuan, Z.;Jun, C..Microwave characteristics of low density flaky magnetic particles[J].Journal of Magnetism and Magnetic Materials,2013:15-20. |
[18] | Delogu, F. .Mechanical processing of Fe powders[J].Journal of Materials Science,2012(11):4757-4762. |
[19] | Gusev AI;Kurlov AS .Production of nanocrystalline powders by high-energy ball milling: model and experiment[J].Nanotechnology,2008(26):265302-1-265302-8-0. |
[20] | Liu, J.;Feng, Y.;Qiu, T. .Synthesis, characterization, and microwave absorption properties of Fe40 wt%Ni alloy prepared by mechanical alloying and annealing[J].Journal of Magnetism and Magnetic Materials,2011(23):3071-3076. |
[21] | Jun Sun;Huailiang Xu;Yang Shen.Enhanced microwave absorption properties of the milled flake-shaped FeSiAl/graphite composites[J].Journal of Alloys and Compounds: An Interdisciplinary Journal of Materials Science and Solid-state Chemistry and Physics,2013:18-22. |
[22] | 郑锋,顾华志,黄璞,汪厚植,冯大军.机械合金化制备纳米晶Fe-Si合金的研究[J].粉末冶金技术,2006(06):434-436,440. |
[23] | 李黎瑛,张振忠,赵芳霞,寿奉良.高能球磨法制备超细镍粉的研究[J].表面技术,2012(04):74-76. |
[24] | 周廷栋,邓龙江,梁迪飞,余志海.FeSiAl纳米晶片状微粉的结构及磁性能研究[J].金属热处理,2008(03):36-39. |
[25] | 葛副鼎,朱静,陈利民.超微颗粒吸收与散射截面[J].电子学报,1996(06):82. |
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