高性能AB5型贮氢合金的成分设计

金属功能材料, 2002, 9(5): 1-6. doi: 10.3969/j.issn.1005-8192.2002.05.001

高性能AB5型贮氢合金的成分设计

张羊换 ^1, , 王新林 ^2, , 陈梅艳 ^3, , 李平 ^4, , 林玉芳 ^5, , 李蓉 ^6,

1.钢铁研究总院功能材料研究所,北京,100081;包头钢铁学院材料系,内蒙古,包头,014010

2.钢铁研究总院功能材料研究所,北京,100081

3.包头钢铁学院材料系,内蒙古,包头,014010

4.钢铁研究总院功能材料研究所,北京,100081

5.钢铁研究总院功能材料研究所,北京,100081

6.钢铁研究总院功能材料研究所,北京,100081

关键词： AB5型贮氢合金 , 化学成分 , 电化学性能

Design of Chemical Compositions on AB5-Type Hydrogen Storage Alloy With High Quality

贮氢合金是MH-Ni电池技术的核心,而其化学成分是决定贮氢合金性能的主要因素.在分析MH-Ni电池对负极材料的性能要求及电极失效机理的基础上,详细讨论了AB5型贮氢合金的主要电化学性能与各种合金元素之间的关系,提出了高性能AB5型贮氢合金成分设计的总体思路和应考虑的各种因素.

参考文献

[1]	王超群;靳红梅 .[J].电源技术,1998,22(03):107.
[2]	陈长聘,王春生.高性能贮氢电极合金[J].物理,1998(03):156.
[3]	Willems J J G .[J].Philips Journal of Research,1984,39(01):1.
[4]	Mukerjee S;McBreen J et al.[J].Journal of the Electrochemical Society,1995,142(10):3429-3433.
[5]	王连邦 .[J].金属功能材料,1999,6(06):105-110.
[6]	郭靖洪,燕萍,庞柳萍,唐丽新,张建海,夏春明,段秋生,刘国忠.贮氢合金Ml（Ni Co Mn Al）s中Ce和Nd对MH-Ni电池性能的影响[J].电源技术,2000(05):265-266,287.
[7]	黄振谦,申建斌,唐有根,刘开宇.Co含量对MH-Ni电池性能的影响[J].电源技术,2001(04):283-285.
[8]	Sakai T;Oguro K et al.[J].Journal of the Less-Common Metals,1990,161:193-202.
[9]	江建军;孙大林;王春生等.[J].金属学报,1995,31:B379-B383.
[10]	Ye H;Zhang H;Wu W Q;Huang T S .[J].Journal of Alloys and Compounds,2000,312:68-76.
[11]	谢中伟 .[J].电池,1996,26(03):144-150.
[12]	吕建国,黄靖云,叶志镇.AB5型贮氢合金及其优化设计[J].金属功能材料,2001(04):5-12.
[13]	Makamura H et al.[J].Journal of Alloys and Compounds,1998,281:81-91.
[14]	江建军等.[J].功能材料,1998,29(01):33-37.
[15]	王超群等.[J].电源技术,1998,22(01):5-7.
[16]	靳红梅,李国勋,张昭良,王超群,王瑞坤,孙丽虹.La1-xNdx（NiCoMnAl）5贮氢合金性能研究[J].中国稀土学报,1998(01):22-25.
[17]	Adzic GD.;Reilly JJ.;Mcbreen J.;Mukerjee S.;Kumar MPS. Zhang W.;Srinivasan S.;Johnson JR. .CERIUM CONTENT AND CYCLE LIFE OF MULTICOMPONENT AB(5) HYDRIDE ELECTRODES[J].Journal of the Electrochemical Society,1995(10):3429-3433.
[18]	王超群;靳红梅;王宁等.[J].电源技术,1998,22(03):107-110.
[19]	Bae Dong-Su;Jang Seung-Ju;Hiroshi Yukawa et al.[J].Journal of Materials Transactions,2001,42(06):1112-1118.
[20]	李全安,陈云贵,涂铭旌,桑革,韩满贵,李宁,唐定骧.高性能贮氢合金电极的成分设计[J].电源技术,2000(04):246-250.
[21]	李平 .快淬低钴AB<,5>型和快淬钛基AB<,2>型储氢合金的研究[D].钢铁研究总院,2002.
[22]	沈剑韵;任洪岩;文振怀 .[J].电源技术,1995,19(04):9-11.
[23]	岩仓千秋.[J].日本化学会志(日本),1998(08):1482-1488.
[24]	Meli F;Zuttel A;Suhlapbach L .[J].Journal of Alloys and Compounds,1992,190:17-24.
[25]	李全安,桑革,李建文,陈云贵,涂铭旌.非化学计量比贮氢合金及其电极特性[J].功能材料,2001(02):156-157,163.
[26]	Kodama T .[J].Journal of Alloys and Compounds,1999,289:207-212.
[27]	陈永辉,魏进平,高峰,周伟,张允什,周作祥.MH-Ni电池高倍率循环寿命影响因素探讨[J].电源技术,2001(z1):142-145.
[28]	赖为华;余成洲 .[J].电池,1996,26(04):189-191.
[29]	李传健 .快淬AB<,5>型贮氢合金研究[D].钢铁研究总院,1998.
[30]	Sakai T;Miyamura H N et al.[J].Journal of the Less-Common Metals,1990,159:127.
[31]	Tang Weizhong;Sun Guangfei .[J].Journal of Alloys and Compounds,1994,203:95-198.
[32]	Sakai T et al.[J].Journal of the Less-Common Metals,1990,161:193-202.
[33]	Latroche M et al.[J].Journal of Alloys and Compounds,1995,218:68.
[34]	Chartouni T;Meli F et al.[J].Journal of Alloys and Compounds,1996,241:260.
[35]	Vogt T;Reilly J et al.[J].Journal of the Electrochemical Society,1999,146(01):16.
[36]	Cossianteli J M et al.[J].Journal of Alloys and Compounds,1997,253:642-647.
[37]	Willems J J G .[J].Journal of Philips Research Reports,1984(39):1.
[38]	Adzic GD.;Reilly JJ.;Mcbreen J.;Mukerjee S.;Kumar MPS. Zhang W.;Srinivasan S.;Johnson JR. .CERIUM CONTENT AND CYCLE LIFE OF MULTICOMPONENT AB(5) HYDRIDE ELECTRODES[J].Journal of the Electrochemical Society,1995(10):3429-3433.
[39]	赵东江;王宝忱;蔡称心 .[J].电源技术,1993,2:21.
[40]	Mukerjee S.;Reilly JJ.;Johnson JR.;Adzic G.;Petrov K. Kumar MPS.;Zhang W.;Srinivasan S.;Mcbreen J. .IN SITU X-RAY ABSORPTION SPECTROSCOPY STUDIES OF METAL HYDRIDE ELECTRODES[J].Journal of the Electrochemical Society,1995(7):2278-2286.
[41]	SMITH G;Goudy A J .[J].Journal of Alloys and Compounds,2001,316:93-98.
[42]	张永俊,孙俊才,于志伟,季世军,许晓磊,刘莎.贮氢电极合金的发展（一）[J].金属功能材料,2001(01):9-13.
[43]	Wallace W E;Karllcek R F .[J].Journal of Physical Chemistry,1979,83:1708.
[44]	Pick M A;Wenzl H J .[J].Hydrogen Energy Progress,1877,1:413.
[45]	Rudman P S .[J].Journal of the Less-Common Metals,1983,89:93.
[46]	Schober T J .[J].Journal of the Less-Common Metals,1983,89:63.
[47]	Manchester F D;Khatamian D .[J].Materials Science Forum,1988,31:261.
[48]	周煜;雷永泉;罗永春等.气体雾化贮氢电极合金Ml(Ni,Co,Mn,Al)5的活化性能[J].金属学报,1996,32(08):857-860.
[49]	Iwakura C;Oura T et al.[J].Journal of Electroanalytical Chemistry,1995,398:37.
[50]	Notter P H L;Hokkeling P .[J].Journal of the Electrochemical Society,1991,188(07):1877-1885.
[51]	Tadohoro M .[J].Journal of Alloys and Compounds,1993,192:179-181.
[52]	Wang X H;Wang C S;Chen C P et al.[J].International Journal of Hydrogen Energy,1996,22:479.
[53]	Wang C S;Wang X H;Lei Y Q et al.[J].International Journal of Hydrogen Energy,1997,22:1117.
[54]	潘洪革 .[J].中国有色金属学报,1999,9(01):453-457.
[55]	Chiaka I;Kazujiro F;Hiroshi S et al.[J].Electrochimica Acta,1998,43:2043.
[56]	程菊.镍氢电池及储氢合金的进展[J].金属功能材料,1996(03):86.
[57]	谢中伟 .[J].电池,1996,26(03):144-146.
[58]	Notten P H L;Daams J L C;Einerhand R E F .[J].Physical Chemistry,1992,96:656.
[59]	江建军等.[J].材料导报,1993,6:16-18.

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高性能AB5型贮氢合金的成分设计

Design of Chemical Compositions on AB5-Type Hydrogen Storage Alloy With High Quality

参考文献