用丙烯睛和己二胺可合成环氧树脂固化剂。借助核磁共振(NMR)、红外光谱(IR)、质谱(MS)分析该固化剂组成。结果表明:当己二胺(HMD)、丙烯睛(AN)按摩尔比为1:1反应时,除主要产物氰乙基己二胺外,产物中同时存在二氰乙基己二胺。
The curing agent for epoxy is synthesized by reacting hexamethylenediamine with acrylonitrile.Synthesis method has been improved.The compositions of the curing agent are analyzed with infrared spectroscopy,mass spectroscopy and nuclear magnetic resonance.It is found that when.the reaction between hexamethylenediamine and acrylonitrile is carried out in the mole ratio of 1: 1,main product of the mono-cyanoethylation hexamethylenediamine and by-product of the bicyanoethylation hexamethylenediamine is produced at same time.
参考文献
[1] | Heinz G;Herwig H;Leopold H .Rolf L[P].DE:2446489 |
[2] | Famham A G .[P].US 275323 |
[3] | Geigy J R.[J].Brit |
[4] | Hobgood R T et al.Kinetics of the reaction of imidazole with acrylonitrile by using NMR[J].Journal of Chemical Physics,1993,39:2501. |
[5] | Grasseli J G;Ritchey W M.Atlas of spectral data and physical constants for organic compounds(Volume 3)[M].CRC Press Inc.Ohio,1975:385. |
[6] | WolfC .Spectrochim[J].Acta,1971,27:2109. |
[7] | 王序明.红外光谱100例[M].北京:科学出版社,1984:18. |
[8] | 王序明.红外光谱100例[M].北京:科学出版社,1984:49. |
[9] | 王宗明;何欣翔;孙殿卿.实用红外光谱学[M].北京:中国石化出版社,1978:162. |
[10] | 吴瑾元.近代傅里叶变换红外光谱技术及其运用[M].北京:科学技术文献出版社,1994:603. |
[11] | Hummel D O.Atlas of plymer and plastics alalysis (Vol-ume 2)[J].Weinheim,1984:701. |
上一张
下一张
上一张
下一张
计量
- 下载量()
- 访问量()
文章评分
- 您的评分:
-
10%
-
20%
-
30%
-
40%
-
50%