分析了笼形低聚硅倍半氧烷(POSS)单体的结构特点,评述了它的典型合成方法,介绍了最新合成路线,归纳了POSS纳米材料的基本特征,举例说明了这种无机-有机杂化材料在航空航天领域的潜在用途.指出这种新材料今后的主要发展方向是降低生产成本、研制新的功能化POSS单体、开发性能优良的POSS纳米杂化材料、探讨结构与性能之间关系以能动地设计制造POSS纳米结构材料.
参考文献
[1] | Brown A S .New possibilities for high-temperature polymers[J].Aerospace America,1999,37:3033. |
[2] | Scott D W .Thermal rearrangement of branched-chain methylpolysiloxanes[J].Journal of the American Chemical Society,1946,68(01):356-358. |
[3] | Ronald H. Baney;Maki Itoh;Akihito Sakakibara;Toshio Suzuki .Silsesquioxanes[J].Chemical Reviews,1995(5):1409-1430. |
[4] | Li G;Wang L;Ni H et al.Polyhedral oligomeric silsesquioxane(POSS) polymers and copolymers: a review. J[J].Inorg Organomet Polym,2001,11:123-154. |
[5] | FEHER F J;Terroba R;Jin R.Silsesquioxanes and spherosilicates as precursors to hybrid inorganic/organic materials[J].Polymeric materials science and engineering,2000:301-302. |
[6] | Fryl C L;Collins W T .The oligomeric silsesquioxanes(HSiO3/2)n[J].Journal of the American Chemical Society,1970,92(19):5586-55588. |
[7] | Joseph M. Antonucci;Bruce O. Fowler;Jeffrey W. stansburg .FACILE SYNTHESES OF ACRYLIC ORGANOSILSESQUIOXANES FOR DENTAL APPLICATIONS[J].Polymer Preprints,1997(2):118-119. |
[8] | FEHER F J;Newman D A;Walzer J F .Silsesquioxanes as models for silica surfaces[J].Journal of the American Chemical Society,1989,111(05):1741-1748. |
[9] | Lichtenhan J D;Gilman J W;Feher F J .Process for preparation of polyhedral oligomeric silsesquioxanes and synthesis of polymers containing polyhedral oligomeric silsesquioxane group segments[P].US:5484867,1996. |
[10] | Kinrade SD.;Pole DL.;Syvitski RT.;Knight CTG. .Silicon-29 NMR studies of tetraalkylammonium silicate solutions. 1. Equilibria, Si-29 chemical shifts, and Si-29 relaxation[J].Inorganic Chemistry: A Research Journal that Includes Bioinorganic, Catalytic, Organometallic, Solid-State, and Synthetic Chemistry and Reaction Dynamics,1998(17):4272-4277. |
[11] | Kinrade SD.;Pole DL.;Syvitski RT.;Knight CTG. .Silicon-29 NMR studies of tetraalkylammonium silicate solutions. 2. Polymerization kinetics[J].Inorganic Chemistry: A Research Journal that Includes Bioinorganic, Catalytic, Organometallic, Solid-State, and Synthetic Chemistry and Reaction Dynamics,1998(17):4278-4283. |
[12] | FEHER F J;Terroba R;Jin Renzhi.Controlled partial hydrolysis of spherosilicate frameworks: synthesis of endo - Me3SiO) 6 Si6 O7 ( OH ) 4 ] and endo- ( Me3 SiO)6 Si6 O7 { OSiMe2 ( CH = CH2 ) } 4 ] from Me3 SiO) 6 Si6 O9 ][J].Chemical Communications,1999:2513-2514. |
[13] | 张亚峰,孙陆逸,刘安华,龚克成.笼型六面体倍半硅氧烷衍生物制备聚合物纳米复合材料[J].化学世界,2001(02):98-102. |
[14] | Lichtenhan J D;Schwab J .Commercialization, properties, and applications for nanostructured hybrid POSS chemical feedstock technology[J].Polymeric Preprints(American Chemical Society Division of Polymer Chemistry),2000,41:527-528. |
[15] | Gilman J W;Kashiwagi T T;Lichtchan J D .Nanocomposites: a revolutionary new flame retardant approach[J].SAMPE Journal,1997,33(04):40-46. |
[16] | Mark W. Ellsworth;Douglas L. Gin .Recent advances in the design and synthesis of polymer-inorganic nanocomposites[J].Polymer News,1999(10):331-341. |
[17] | Haddad T S;Stapleton R;Jeon H G et al.Nanostructured hybrid organic/inorganic materials[J].Polymeric Preprints(American Chemical Society Division of Polymer Chemistry),1999,40:496-497. |
[18] | JIA W .Dental composite materials and method of manufacture thereof[P].US2002198282,2002. |
[19] | Joseph S C;James B A .Polymeric biomaterials containing silsesquioxane monomers[P].US2002128414,2002. |
[20] | Viers B;Phillips S;Haddad T et al.Model polyhedral oligomeric silsesquioxane thin films for coating applications[J].International SAMPE Symposium and Exibition,2002,47:1508-1516. |
[21] | Leu CM.;Reddy GM.;Wei KH.;Shu CF. .Synthesis and dielectric properties of polyimide-chain-end tethered polyhedral oligomeric silsesquioxane nanocomposites[J].Chemistry of Materials,2003(11):2261-2265. |
[22] | Phillips S H;Gonalez R I;Chaffee P et al.Remarkable AO resistance of POSS inorganic/organic polymers[J].International SAMPE Symposium and Exibition,2000,45:1921-1932. |
[23] | Liu Q;Schwab J J;Lichtenhan J D.Optically clear POSS polymeric materials[J].Polymeric materials science and engineering,2002:97-98. |
[24] | FireQuench 1287[DB/OL].http:∥www. hybridplastics. com/FQ1287,2004-7-6. |
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