以SiO2气凝胶为研究对象,对其气相和固相导热机理进行了研究,进而为SiO2气凝胶材料传热设计提供理论指导.建立了SiO2气凝胶固相结构单元导热模型,在考虑对声子平均自由程的各种限制条件基础上,运用动力学理论分析了影响SiO2气凝胶固相结构单元热导率的影响因素.根据SiO2气凝胶微观结构特点,建立了几种纳米孔隙模型,计算了各种条件下SiO2气凝胶的当量热导率,研究了SiO2气凝胶各物性参数对其当量热导率的影响,并对比了几种纳米孔隙模型下SiO2气凝胶的当量热导率,并与实验值做了比较.
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