硅氧氮陶瓷先驱体的合成及表征

宇航材料工艺 , 2011, 41(1): 93-95. doi: 10.3969/j.issn.1007-2330.2011.01.022

硅氧氮陶瓷先驱体的合成及表征

罗晶 ^1, , 张宗波 ^2, , 罗永明 ^3, , 彭志坚 ^4, , 徐彩虹 ^5,

1.中国地质大学,北京,100083

2.中国科学院化学研究所,北京,100190

3.中国科学院化学研究所,北京,100190

4.中国地质大学,北京,100083

5.中国科学院化学研究所,北京,100190

关键词：硅氧氮陶瓷 , 聚合物先驱体 , 合成

Synthesis and Characterization of Silicon Oxynitride Ceramic Precursor

以MeViSiCl2、MeHSiCl2和MeSiCl3为原料,采用先部分水解再氨解的方法制备了硅氧氮陶瓷先驱体.利用FT-IR、1H-NMR、29Si-NMR、GPC以及TGA对聚合物先驱体的结构和热性能进行了表征.结果表明:合成的硅氧氮烷在DCP固化2 h后具有77.7%的陶瓷产率.

参考文献

[1]	Sglavo V M;Masehio R D;Soraru G D .Fabrication and eharacterization of polymer-derived Si2N2O-ZrO2 nanoeomposite ceralrlics[J].Journal of Materials Science,1993,28:6437.
[2]	张俊宝,温广武,贾德昌,雷廷权,周玉.硅氧氮陶瓷的先驱体法合成及性能的研究[J].航空材料学报,2001(03):39-42.
[3]	Tong O F;Wang J Y;Li Z P et al.Low-temperature synthesis/densification and properties of Si2 N2 O prepared with Li2O additive[J].Journal of the European Ceramic Society,2007,27:4767.
[4]	Ohashi M;Kanzaki S;Tabata H .High-temperature flexural strength of hot@pressed silicon oxynitride ceramics[J].Journal of Materials Science Letters,1988,7:339-340.
[5]	Ohashi M;Kanzaki S;Tabata H .Effect of additives on some properties silicon oxynitride ceramics[J].Journal of Materials Science,1991,26:2608-2614.
[6]	Rocabois P.;Bernard C.;Chatillon C. .THERMODYNAMICS OF THE SI-O-N SYSTEM .2. STABILITY OF SI2N2O(S) BY HIGH-TEMPERATURE MASS SPECTROMETRIC VAPORIZATION[J].Journal of the American Ceramic Society,1996(5):1361-1365.
[7]	张俊宝,雷廷权,温广武,周玉.氮氧化硅合成研究进展[J].材料科学与工艺,2001(04):434-441.
[8]	ChoHona G;Hany R;Vogta U et al.Silicon-29 MA S-NMR study of α-silicon nitride and alno rphous silicon oxynit ridefibres[J].Journal of the European Ceramic Society,1998,18(05):535-541.
[9]	Funayama T;Arain M;Nishii H et al.Polysiloxagalles,silicon oxynitride fibers and processes for producing same[P].EPP 0 237 199,1987-02-12.
[10]	Sckine M;Katayama S .Preparation of silicon oxynitride Shss fibers by ammonolysis of silica gels[J].Journal of Non-Crystalline Solids,1991,134:199-207.
[11]	Muealo M R;Milestone N B;Vickridge I C et al.Preparation of ceramic coatings from pre-ceramic precursors[J].Journal of Materials Science,1994,29:4487-4499.
[12]	刘洪丽,黄志求,高晶,荣守范.不同陶瓷先驱体的裂解过程及粘接性能[J].材料科学与工程学报,2008(06):865-868.
[13]	Yu G E;Edirisinghe M;Finch D et al.Synthesis of silicon oxynitride from a polymeric Precursor.Part Ⅳ Pyrolysis of the copolymers[J].Journal of Materials Science,1995,30(21):5373.

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材料期刊网

硅氧氮陶瓷先驱体的合成及表征

Synthesis and Characterization of Silicon Oxynitride Ceramic Precursor

参考文献