开发高可靠性的绝缘层薄膜几十年来一直是TFEL显示器研制中的重要努力方向之一.采用双靶脉冲电子束蒸发法制备了Al2O3/TiO2单元结构为10 nm/10 nm、20 nm/20 nm、40 nm/40 nm、总厚度约600 nm的多层复合薄膜,同时采用共蒸发法制备了800 nm的AlxTiyOz复合薄膜,研究了它们的介电性能,并与Al2O3、TiO2单层膜的介电性能做了比较,最后将性能较优的AlxTiyOz薄膜应用到ZnS:Mn TFEL器件中.Al2O3/TiO2多层复合膜随着结构单元中Al2O3、TiO2厚度由10 nm增至40 nm,介电常数由20.2减小到16.1,击穿场强由154 MV/m增至174 MV/m,反映介电损耗的参数ΔVy由0.09 V降为0.04 V,在50 MV/m下漏电流密度由1×10-6 A/cm2增至1×10-4 A/cm2,品质因子由2.62 μC/cm2降为2.46 μC/cm2.AlxTiyOz薄膜的品质因子大于3.6 μC/cm2,应用于ZnS:Mn TFEL器件中获得在200 Hz下较高的L50(58 cd·m-2)、很低的阈值电压(60~70 V),而且各个像素的L-V性能有很好的重复性.
参考文献
[1] | 李文连.有机EL与无机EL和LCD的比较及其未来前景[J].液晶与显示,2002,17(1):28-32. |
[2] | Inoguchi T,Takeda M,Kakihara Y,et al.Stable high luminance thin film electroluminescent panels[C]//SID Int.Symp.Digest,Los Angeles,1974:84-85. |
[3] | Omari M A,Sorbello R S,Aita C R.Crystallization and (Al,Ti)-oxide growth in annealed TiO2-Al2O3 multilayers[J].J.Vac.Sci.Technol.A,2006,24(2):317-323. |
[4] | Kuo D H,Tzeng K H.Growth and properties of titania and aluminium titanate thin films obtained by r.f.magnetron sputtering[J].Thin Solid Films,2002,420-421:497-502. |
[5] | Leinen D,Lassaletta G,Fernanclez,A,et al.Ion beam induced chemical vapor deposition procedure for the preparation of oxide thin films.II.Preparation and characterization of AlxTiyOz thin films[J].J.Vac.Sci.Technol.A,1996,14(5):2842-2848. |
[6] | Kuo D H,Shueh C N.Growth of chemical vapor deposition aluminium titanate films at different CO2/H2 and aluminum butoxide inputs[J].J.Vac.Sci.Technol.A,2004,22(1):151-157. |
[7] | Innocenzi P,Martucci A,Armelao L,et al.Sol-gel synthesis of β-Al2TiO5 thin films at low temperature[J].Chem.Mater.,2000,12(2):517-524. |
[8] | Triani G,Evans P J,Mitchell D R G,et al.Atomic layer deposition of TiO2/Al2O3 films for optical applications[C]//Proceedings of SPIE-The International Society for Optical Engineering,2005,5870:1-10. |
[9] | Tornqvist R,Pitkanen T.Insulative film for thin film structures:US,6388378[P].2002-05-14. |
[10] | Sanchez-Agudo M,Sariano L,Quiros C,et al.Electronic interaction at the Al2O3-TiO2 interface as observed by x-ray absorption spectroscopy[J].Surf.Sci.,2001,482-485:479-475. |
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