根据亚规则溶液模型,进行锰铜二元系的热力学计算表明,γMn-Cu合金在(γ+α)亚稳互溶区确实存在Spinodal分解,在400~600oC时效发生Spinodal分解的是浓度范围为60~90at%Mn的合金。与硬度法相比,采用测量尼尔点来确定Spinodal分解的区域较为可靠。
Sub-regular solution model is used to calculate the thermodynamic of γ Mn-Cu alloy. It is revealed that there exists Spinodal decomposition in (γ+α) metastable miscibility gap. For the Mn-Cu alloy with composition of 60~90 at% Mn Spinodal decomposition will occurs during aging at 400~600oC. The Spinodal decomposition range measured by TN point is more reliable than by hardness.
参考文献
[1] | Schethy L M;Perkins J .The quite alloys[J].Machine Design,1978,50(08):202-206. |
[2] | Sugimoto K;Mori T;Shiode S .Effect of composition on the internal friction and Young` s modulus in γ-phase Mn-Cu alloys[J].Metal Science Journal,1973,7:103-108. |
[3] | Vitek J M;Warlimont H .On a metastable miscibility gap in γ Mn-Cu alloys and the origin of their high damping capacity[J].Metal Science Journal,1976,10:7. |
[4] | Adachi K;Yamashita T;Taneda Y et al.Dynamical transformation electron microscopy microstructure associated with electron phonon interaction in high damping Cu-Mn alloys[J].Philosophical Magazine A:Physics of Condensed Matter:Structure,Defects and Mechanical Properties,1996,73(04):1009-1034. |
[5] | 衣虎春;葛庭燧 .时效对Mn-Cu-Al三元合金内耗、杨氏模量和力学性能的影响[J].金属学报,1988,24(10):A317. |
[6] | Smith J H;Vance E R .Decomposition of γ-phase manganese copper alloys[J].Journal of Applied Physics,1969,40(12):4853. |
[7] | Gaulin B D;Spooner S .Kinetics of phase separation in Mn0 67Cu0 33[J].Physical Review Letters,1987,59:668-671. |
[8] | Vintaykin Y Z;Dmitriyer V B;Udovenko V A .Spinodal decomposition in manganese copper alloys[J].Physics of Metals and Metallography,1978,46(04):97-102. |
[9] | 胡赓祥.锰铜系高阻尼合金中调幅分解的电子显微研究[J].电子显微学报,1984(04):50. |
[10] | Cahn J W .On Spinodal decomposition[J].Acta Materialia,1961,9:795-800. |
[11] | Krenzer R W;Pool M J .With Appendix by Kaufman L Thermodynamic properties of copper-manganese alloys[J].Transactions of the Metallurgical Society of AIME,1969,245:91-98. |
[12] | Millert M;Staffansson L-I .[J].Acta Chemica Scandinavica,1970,24:3618-3626. |
[13] | Lewin K;Sichen D;Seetharaman S .Thermodynamic study of the Cu-Mn system[J].Scandinavian Journal of Metallurgy,1993,22(06):310-315. |
上一张
下一张
上一张
下一张
计量
- 下载量()
- 访问量()
文章评分
- 您的评分:
-
10%
-
20%
-
30%
-
40%
-
50%