以 H2O作氧源, Zn(C2H5)2作 Zn源, N2作载气,以 GaN/Al2O3为衬底采用常压 MOCVD技术 生长了高质量的 ZnO单晶膜.用 X射线双晶衍射技术测得其对称衍射 (0002)面ω扫描半峰宽 ( FWHM)为 404arcsec,表明所生长的 ZnO膜具有相当一致的 C轴取向;其对称衍射( 0004)面ω- 2θ扫描半峰宽为 358arcsec,表明所生长的 ZnO单晶膜性能良好;同时,该 ZnO薄膜的非对称衍射 (1012)面ω扫描半峰宽为 420arcsec,表明所生长的 ZnO膜的位错密度为 108cm- 2,与具有器件质 量的 GaN材料相当.
参考文献
[1] | Hichernell F S .Microstructure of ZnO film used for acoustic surface- wave generation[J].Journal of Vacuum Science and Technology,1975,12(04):879-883. |
[2] | H. Kim;C. M. Gilmore;J. S. Horwitz .Transparent conducting aluminum-doped zinc oxide thin films for organic light-emitting devices[J].Applied physics letters,2000(3):259-261. |
[3] | Horsthuis W H G .ZnO Processing for integrated optic senors[J].Thin Solid Films,1986,137(02):185-192. |
[4] | Traversa E;Bearzotti A .A novel humidity- dectection mechanism for ZnO dense pellets[J].Sensors and Actuators,1995,B23(2-3):181-186. |
[5] | Basu S;Dutta A .Modified heterojunction based on zinc oxide thin films for hydrogen gas- sensor application[J].Sensors and Actuators,1994,B22(02):83-87. |
[6] | Y. LIU;C.R. GORLA;S. LIANG .Ultraviolet Detectors Based on Epitaxial ZnO Films Grown by MOCVD[J].Journal of Electronic Materials,2000(1):69-74. |
[7] | Koch MH.;Lamb RN.;Timbrell PY. .THE INFLUENCE OF FILM CRYSTALLINITY ON THE COUPLING EFFICIENCY OF ZNO OPTICAL MODULATOR WAVEGUIDES[J].Semiconductor Science and Technology,1995(11):1523-1527. |
[8] | Kin Y J;Kim K W .[J].Japanese Journal of Applied Physics,1997,36(4A):2277-2280. |
[9] | Vispute R D;Talyansky V;Trajanovic Z et al.High quality crystalline ZnO buffer layers on sapphire(001) by pulsed laser deposition for Ⅲ-Ⅴ nitrides[J].Applied Physics Letters,1997,70(20):2735-2737. |
[10] | Gorla C.R.;Emanetoglu N.W.;Liang S.;Mayo W.E.;Lu Y.;Wraback M.;Shen H. .Structural, optical, and surface acoustic wave properties of epitaxial ZnO films grown on (011 over-bar 2) sapphire by metalorganic chemical vapor deposition[J].Journal of Applied Physics,1999(5):2595-0. |
[11] | Kang H B;Nakamura K;Yoshida K et al.Single- crystalline ZnO films grown on(001) Al2O3 substrate by electron cyclotron resonance- assisted molecular beam epitaxy technique[J].Journal of Applied Physiology,1997,36(7B):L933-L935. |
[12] | Sang B;Konagai M .Growth of transparent conductive oxide ZnO films by atomic layer deposition[J].Japanese Journal of Applied Physics,1996,35(5B):L602-L605. |
[13] | Mineo Hiramatsu;Koichi Imaeda;Noriaki Horio;Masahito Nawata .Transparent conducting ZnO thin films prepared by XeCl excimer laser ablation[J].Journal of Vacuum Science & Technology, A. Vacuum, Surfaces, and Films,1998(2):669-673. |
[14] | Johnson M A L;Fujita S;Rowland et al.MBE growth and properties of ZnO on sapphire and SiC substrate[J].Journal of Electronic Materials,1996,25(05):855-862. |
[15] | Sun X W;Kwok H S .Optical properties of epitaxially grown zinc oxide films on sapphire by pulsed laser deposi- tion[J].Journal of Applied Physics,1999,86(01):408-411. |
[16] | Hong SK.;Chen YF.;Hanada T.;Yao T.;Ko HJ. .Control and characterization of ZnO/GaN heterointerfaces in plasma-assisted MBE-grown ZnO films on GaN/Al2O3[J].Applied Surface Science: A Journal Devoted to the Properties of Interfaces in Relation to the Synthesis and Behaviour of Materials,2000(0):441-448. |
[17] | ATAEV B M;Lundin W V;Mamedov V V et al.Low- pressure chemical vapour deposition growth of high- quality ZnO films on epi- GaN/α- Al2O3[J].Journal of Physics:Condensed Matter,2001,13:L211-L214. |
[18] | Baijun Zhao;Hongjun Yang;Guotong Du;Guoqing Miao;Yuantao Zhang;Zhongmin Gao;Tianpeng Yang;Jinzhong Wang;Wancheng Li;Yan Ma;Xiaotian Yang;Boyang Liu;Dali Liu;Xiujun Fang .High-quality ZnO/GaN/Al_2O_3 heteroepitaxial structure grown by LP-MOCVD[J].Journal of Crystal Growth,2003(1/2):130-134. |
[19] | 吕建国,汪雷,叶志镇,赵炳辉.ZnO薄膜应用的最新研究进展[J].功能材料与器件学报,2002(03):303-308. |
[20] | 陈诺夫,修慧欣,杨君玲,吴金良,钟兴儒,林兰英.用X射线双晶衍射方法测定GaMnAs组分[J].科学通报,2001(24):2035-2038. |
[21] | 黄胜涛.固体 X射线学 (一 )[M].北京:高等教育出版社,1985 |
[22] | Vook R W;Matthews J W.Epitaxial Growth[M].New York:Academic,1975:339. |
[23] | Heying B;Wu X H;Keller S et al.Role of threading dislocation structure on the x- ray diffraction peak widths in epitaxial GaN films[J].Applied Physics Letters,1996,68:643-645. |
上一张
下一张
上一张
下一张
计量
- 下载量()
- 访问量()
文章评分
- 您的评分:
-
10%
-
20%
-
30%
-
40%
-
50%