新型空穴传输材料N,N'-二(α-萘基)-N,N'-二苯基-4,4'-联萘胺的合成与光电性质

功能材料与器件学报 , 2006, 12(5): 451-455. doi: 10.3969/j.issn.1007-4252.2006.05.019

新型空穴传输材料N,N'-二(α-萘基)-N,N'-二苯基-4,4'-联萘胺的合成与光电性质

黄丽群 ^1, , 刘艳珠 ^2, , 杨长剑 ^3, , 易春 ^4, , 刘坚 ^5, , 高希存 ^6,

1.南昌大学理学院化学系,南昌330047;景德镇陶瓷学院材料科学与工程学院,景德镇333001

2.南昌大学理学院化学系,南昌330047

3.南昌大学理学院化学系,南昌330047

4.南昌大学理学院化学系,南昌330047

5.南昌大学理学院化学系,南昌330047

6.南昌大学理学院化学系,南昌330047

基金项目: 教育部留学回国人员科研启动基金(Z-02873) 江西省教育厅科研项目(Z-02803)

关键词：空穴传输材料 , N,N'-二(α-萘基)-N,N'-二苯基-4,4'-联萘胺(α-NPN) , 玻璃化温度 , 量子效率 , 氧化电势

Novel hole-transporting materials: synthesis and photoelectric properties of N,N'-di(α-naphthyl) -N,N'-diphenyl-4,4'-naphthidine

以4,4'-联萘胺为母体,以最常用的空穴传输材料N,N'-二(α-萘基)-N,N'-二苯基-4,4'-联苯胺(α-NPD)为样板,合成了新型空穴传输材料N,N'-二(α-萘基)-N,N'-二苯基-4,4'-联萘胺(α-NPN).通过核磁共振氢谱和元素分析进行了结构表征.差热分析测定其玻璃化温度(Tg)达到128 ℃.相对于α-NPD,α-NPN的吸收光谱和光致发光光谱都发生了红移.循环伏安法测定其氧化电势为1.20V,比α-NPD的1.02V稍高.该化合物可发明亮的蓝色荧光 (461 nm),积分球测定其薄膜荧光量子效率为8.5%,比α-NPD的5.5%高.初步确定α-NPN可作为有机电致发光空穴传输材料.

参考文献

[1]	Shirota Y;Kobata T;Noma N.Starburst molecules for amorphous molecular materials.4,4′,4′′-tris(N,N-diphenylamino)triphenylamine and 4,4′,4′′-tris[N-(3-methylphenyl)-N-pheny lamino] triphenylamine[J].Chemistry Letters,1989:1145-1148.
[2]	O'Brien DF.;Forrest SR.;Koene BE.;Loy DE.;Thompson ME.;Burrows PE. .Hole transporting materials with high glass transition temperatures for use in organic light-emitting devices[J].Advanced Materials,1998(14):1108-1112.
[3]	Junji K;Yasuhirp L .Fabrication of highly efficient organic electroluminescent devices[J].Applied Physics Letters,1998,73(19):2721-2723.
[4]	K.R.Justin Thomas;Jiann T.Lin;Yu-Tai Tao .Light-Emitting Carbazole Derivatives: Potential Electroluminescent Materials[J].Journal of the American Chemical Society,2001(38):9404-9411.
[5]	Yamamoto T;Nishiyama M;Yasuyuki K .Palladium-Catalyzed synthesis of triarylamines from aryl halides and diarylamines[J].Tetrahedron Letters,1998,39(16):2367-2370.
[6]	Chen Guo-zhen;Huang Xian-zhi;Zheng Zhu-zi.Fluorescence Analysis[M].北京:科学出版社,1990
[7]	Tang C W;Chen C H;VanSlyke S A .Organic electroluminescent devices with improved stability[J].Applied Physics Letters,1996,69(15):2160-2162.
[8]	丁邦东,张积梅,朱文清,郑新友,吴有智,蒋雪茵,张志林,许少鸿.一种简便测定有机电致发光材料能级的电化学方法[J].发光学报,2003(06):606-611.
[9]	Thelakkat M.;Schmidt HW. .Synthesis and properties of novel derivatives of 1,3,5-tris(diarylamino)benzenes for electroluminescent devices[J].Advanced Materials,1998(3):219-223.
[10]	Arkhipov VI.;Tak YH.;Bassler H.;Emelianova EV. .Charge injection into light-emitting diodes: Theory and experiment[J].Journal of Applied Physics,1998(2):848-856.

上一张下一张

计量

下载量()
访问量()

作者相关

文章评分

您的评分：
1

0%
2

0%
3

0%
4

0%
5

0%

材料期刊网