采用离子交换结合热处理法,制备出银纳米颗粒-硅酸盐玻璃复合材料.利用紫外-可见光 分光光度计测量吸收光谱,利用Z-scan技术测量三阶非线性光学效应.研究结果表明,离子交换的最佳温度范围为310℃-380℃,提高离子交换温度和熔盐中AgNO3浓度,延长离子交换时间,有利于在玻璃中引入更多的银离子.玻璃中引入的银离子浓度越高,高温热处理后玻璃中银纳米颗粒的体积分数越大.含铁玻璃有利于银纳米颗粒的形成.随着热处理温度的提高和时间的延长,银纳米颗粒尺寸和颗粒体积分数增大,共振吸收峰红移.通过离子交换结合热处理方法可以获得具有优良三阶非线性光学性能的银纳米颗粒-硅酸盐玻璃复合材料,其在非等离子体共振区域的三阶非线性系数可达1.16×10-10esu,其中实部为-1.15×10-10esu,虚部为1.4×10-11esu.
参考文献
| [1] | Cotter D;Manning R J;Blow K J et al.Nonlinear optics for high-speed digital information processing[J].Science,1999,286:1523. |
| [2] | Eaton D F .Nonlinear optical materials[J].Science,1991,253:281. |
| [3] | Wang WT.;Yang G.;Chen ZH.;Zhou YL.;Lu HB.;Yang GZ. .Iron nanoparticles in amorphous BaTiO3 thin films with large third-order optical nonlinearity[J].Journal of Applied Physics,2002(12):7242-7245. |
| [4] | Yang Y.;Shi JL.;Chen HR.;Dai SG.;Liu Y. .Enhanced off-resonance optical nonlinearities of Au@CdS core-shell nanoparticles embedded in BaTiO3 thin films[J].Chemical Physics Letters,2003(1/2):1-6. |
| [5] | Liu Y;Li D;Zhu R Y et al.Third-order nonlinear optical response of Au-core CdS-shell composite nanoparticles embedded in BaTiO3 thin films[J].Applied Physics B,2003,76:435. |
| [6] | Uchida K;Kaneko S;Omi S et al.Optical nonlinearities of a high concentration of small metal particles dispersed in glass:copper and silver particles[J].Journal of the Optical Society of America B:Optical Physics,1994,11(07):1236. |
| [7] | Roiz J;Oliver A;Munoz E et al.Modification of the optical properties of Ag-implanted silica by annealing in twodifferent atmospheres[J].Journal of Applied Physics,2004,95:1783. |
| [8] | Sendova M;Sendova-Vassileva M;Pivin JC;Hofmeister H;Coffey K;Warren A .Experimental study of interaction of laser radiation with silver nanoparticles in SiO2 matrix[J].Journal of nanoscience and nanotechnology,2006(3):748-755. |
| [9] | Gonella F;Mazzoldi P.Metal nanocluster composite glasses[M].New York:Academic Press,Inc,2000:81. |
| [10] | Yang X C;Du T L;Hofmeister H et al.In situ synthesis of silver nanoparticles in soda-lime silicate glasses by ion -exchange method[J].Journal of the Chinese Ceramic Society,2005,33(11):1371. |
| [11] | 杨修春,杜天伦,陈爽,熊定邦,赵景泰,黄文旵.光谱学研究银纳米颗粒在玻璃中的生成规律[J].功能材料与器件学报,2006(03):177-181. |
| [12] | Paje SE.;Garcia MA.;Llopis J.;Villegas MA. .Optical spectroscopy of silver ion-exchanged As-doped glass[J].Journal of Non-Crystalline Solids: A Journal Devoted to Oxide, Halide, Chalcogenide and Metallic Glasses, Amorphous Semiconductors, Non-Crystalline Films, Glass-Ceramics and Glassy Composites,2003(3):239-247. |
| [13] | Cai W;Hofmeister H;Dubiel M .Importance of lattice contraction in surface plasmon resonance shift for free and embedded silver particles[J].European Physical Journal D:Atomic Molecular and Optical Physics,2001,13:245. |
| [14] | Hacke F;Ricard D;Flytzanis C .Optical nonlinearities of small metal particles:surface-mediated resonance and quantum size effects[J].Journal of the Optical Society of America B:Optical Physics,1986,3(12):1647. |
| [15] | Kreibig U;Vollmer M.Optical Properties of Metal Clusters[M].Berlin:springer-verlag,1995:300. |
| [16] | Sheik-Bahae M.;Said A.A. .Sensitive measurement of optical nonlinearities using a single beam[J].IEEE Journal of Quantum Electronics: A Publication of the IEEE Quantum Electronics and Applications Society,1990(4):760-769. |
| [17] | Wang P;Lu Y;Tang L et al.Surface-enhanced optical nonlinearity of a gold film[J].Optics Communications,2004,229:425. |
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