In this paper, we report on long- persistence white phosphor SrAl2Si2O8 :Eu2+ , Dy3+ synthe-sized by the sol - gel method. The luminescent materials prepared by the sol - gel method have many ad-vantages, such as uniform composition, high purity, fine grains and low synthesis temperature. We foundthat SrAl2Si2O8 :Eu2+ ,Dy3+ phosphor prepared by the sol -gel method can provide more luminescent in-tensity and better afterglow characteristic compared with the same phosphor prepared by solid -statemethod. Namely, the particle size and shape of phosphors should be optimized to obtain the maximumquantum efficiency through energy absorption. The mierostrueture of the phosphor consisted of regularfine grains with an average size of about 0.5. - 1 μm. Under 356 nm light excitation, the broadband emis-sion of the phosphor continues from 350 to 650 ntn and the emission peak is at about 414 nm, which canbe viewed as the typical emission of Eu2+ ascribed to the 4f→5d transitions.
参考文献
[1] | Poort S H M;Blokpoel W P .Luminescence of Eu2+ in barium and strontium aluminate and gallate[J].Chemistry of Materials,1995,7:1547-1551. |
[2] | Kim JS;Jeon PE;Park YH;Choi JC;Park HL;Kim GC;Kim TW .White-light generation through ultraviolet-emitting diode and white-emitting phosphor[J].Applied physics letters,2004(17):3696-3698. |
[3] | Wang Y;Wang Z;Zhang P et al.Preparation of Eu2+ and Dy3+ co-activated CaAl2Si2O8 -based phosphor and its optical properties[J].Materials Letters,2004,58:3308-3312. |
[4] | Wang Z;Wang YH;Zhang PY;Fan XP;Qian GD .Tunable afterglow color in Eu2+ and Dy3+ co-activated alkaline earth feldspar solid solutions phosphors[J].Journal of Luminescence: An Interdisciplinary Journal of Research on Excited State Processes in Condensed Matter,2007(1):140-142. |
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