磨料是化学机械抛光(CMP)中重要的组成部分,是决定抛光平坦化的重要影响因素.采用两步法制备了新型的氧化硅包覆聚苯乙烯(PS)核壳型复合磨料,采用扫描电子显微镜( SEM)、透射电子显微镜(TEM),X射线能量色散谱(EDX)等对复合磨料进行了表征.结果表明所制备的复合磨料具有核壳结构,且表面光滑.随后复合磨料对比硅溶胶对铜化学机械抛光进行研究,采用原子力显微镜( AFM)观测表面的微观形貌,并测量了表面粗糙度.经过复合磨料抛光后的铜片粗糙度为0.58nm,抛光速率为40nm/min.硅溶胶抛光后的铜片的粗糙度是1.95nm,抛光速率是37nm/min.
参考文献
[1] | 刘玉岭,李嘉席,檀柏梅,梁存龙.ULSI制备中多层布线导体铜的抛光液与抛光技术的研究[J].电子工业专用设备,2007(10):17-21. |
[2] | Matijevic E;Babu SV .Colloid aspects of chemical-mechanical planarization[J].Journal of Colloid and Interface Science,2008(1):219-237. |
[3] | 孙薇,刘玉岭,张伟,时慧玲,侯丽辉.ULSI多层Cu布线CMP中磨料的研究[J].半导体技术,2008(08):662-665. |
[4] | 李庆忠,郭东明,康仁科.ULSI制造中铜CMP抛光液的技术分析[J].半导体技术,2007(05):382-386. |
[5] | 胡建东,李永绣,周雪珍.铜在含碘酸钾的CeO2浆料中CMP的抛光速率及影响因素的研究[J].有色金属(冶炼部分),2007(04):53-55. |
[6] | S.V. Babu;Y. Li;A. Jindal .Chemical-Mechanical Planarization of Cu and Ta[J].JOM,2001(6):50-52. |
[7] | Nam-Hoon Kim;Jong-Heun Lim;Sang-Yong Kim .Effects of phosphoric acid stabilizer on copper and tantalum nitride CMP[J].Materials Letters,2003(29):4601-4604. |
[8] | Shao-Yu Chiu;Ying-Lang Wang;Chuan-Pu Liu;Shih-Chieh Chang;Gwo-Jen Hwang;Ming-Shiann Feng;Chia-Fu Chen .High-selectivity damascene chemical mechanical polishing[J].Thin Solid Films: An International Journal on the Science and Technology of Thin and Thick Films,2006(1/2):60-63. |
[9] | Steigerwald J M;Murarka S P;Ho J et al.Mechanisms of copper removal during chemical mechanical polishing[J].Journal of Vacuum Science and Technology B:Microelectronics and Nanometer Structures,1995,13(06):2215-2218. |
[10] | Feng MS;Chiu SY;Dai BT;Tsai MS;Tung IC;Hu TC .Nitric acid-based slurry with citric acid as an inhibitor for copper chemical mechanical polishing[J].Materials Chemistry and Physics,1999(2):169-171. |
[11] | Takaya Y;Tachika H;Hayashi T et al.Performance of water-soluble fullerenol as novel functional molecular abrasive grain for polishing nanesurfaces[J].CIRP Aunals-Manufacturing Technology,2009,58(01):495-498. |
[12] | S. Armini;C. M. Whelan;M. Moinpour .Copper CMP with Composite Polymer Core-Silica Shell Abrasives: A Defectivity Study[J].Journal of the Electrochemical Society,2009(1):H18-H26. |
[13] | Chen M;Zhou SX;Wu LM;Xie SH;Chen Y .Preparation of silica-coated polystyrene hybrid spherical colloids[J].Macromolecular chemistry and physics,2005(18):1896-1902. |
[14] | Caruso F;Caruso R A;Mohwald H .Nanoengineering of inorganic and hybrid hollow spheres by colloidal templating[J].Science,1998,282(5391):1111-1114. |
[15] | Graf C.;Vossen DLJ.;Imhof A.;van Blaaderen A. .A general method to coat colloidal particles with silica[J].Langmuir: The ACS Journal of Surfaces and Colloids,2003(17):6693-6700. |
[16] | Hong J;Han H;HongC K et al.A direct preparation of silica shell on polystyrene microspheres prepared by dispersion polymerization with polyvinylpyrrolidone[J].Journal of Polymer Science Part A: Polymer Chemistry,2008,46(08):2884-2890. |
[17] | Hong, J.;Lee, J.;Rhym, Y.-M.;Kim, D.-H.;Shim, S.E. .Polyelectrolyte-assisted synthesis of polystyrene microspheres by dispersion polymerization and the subsequent formation of silica shell[J].Journal of Colloid and Interface Science,2010(2):410-416. |
[18] | Yu Lu;Joe McLellan;Younan Xia .Synthesis and Crystallization of Hybrid Spherical Colloids Composed of Polystyrene Cores and Silica Shells[J].Langmuir: The ACS Journal of Surfaces and Colloids,2004(8):3464-3470. |
[19] | Hua Zou;Shishan Wu;Qianping Ran .A Simple and Low-Cost Method for the Preparation of Monodisperse Hollow Silica Spheres[J].The journal of physical chemistry, C. Nanomaterials and interfaces,2008(31):11623-11629. |
[20] | Armini S;Whelan CM;Maex K;Hernandez JL;Moinpour M .Composite polymer-core silica-shell abrasive particles during oxide CMP[J].Journal of the Electrochemical Society,2007(8):H667-H671. |
上一张
下一张
上一张
下一张
计量
- 下载量()
- 访问量()
文章评分
- 您的评分:
-
10%
-
20%
-
30%
-
40%
-
50%