介绍一种精确的方法, 在质心坐标系中, 把量子N体系统的整体转动自由度和内部运动自由度完全地分离开来. 对于确定的轨道角动量状态, 找到了一组完备且独立的角动量本征函数基, 它们是坐标分量的齐次多项式, 且满足Laplace方程. 系统中的任何角动量本征函数都可以用这组函数基展开, 组合系数只依赖于内部变量, 称为广义径向函数. 可以简单且明显地推导出广义径向函数所满足的广义径向方程. 函数和方程式都只依赖于(3N-6)个内部变量, 而且个数是有限的.
参考文献
[1] | Wigner E P. Group Theory and its Application to the Quantum Mechanics of Atomic Spectra[M]. New York: Academic Press, 1959. |
[2] | Hirschfelder J O, Wigner E P. Separation of Rotational Coordinates from the Schrdinger Equation for N Particles[J]. Proc Nat Acad Sci, 1935, 21: 113-119. |
[3] | Pack R T, Hirschfelder J O. Separation of Rotation al Coordinates from N-electron Diatomic Schrdinger Equation[J]. J Chem Phys, 1968, 49(9): 4 009-4 020. |
[4] | Lin C D. Hyperspherical Coordinate Approach to Atomic and Other Coulombic Three-body Systems[J]. Phys Rep, 1995, 257(1): 1-83 and references therein. |
[5] | Krivec R, Mandeleig V B. Matrix Elements of Poten tials in the Correlation-function Hyperspherical-harmonic Method[J].Phys Rev A, 1990, 42(7): 3 779-3 788. |
[6] | Tang J Z, Watanabe S, Matsuzawa M. General Computational Method for Two-electron Systems[J].Phys Rev A, 1992, 46(5): 2 437-2 444. |
[7] | Gatti F, Iung C, Menou M, et al. Vector Parametrization of the N-atom Problem in Quantum Mechanics II: Coupled-angular-momentum spectral representations for four-atom systems[J]. J Chem Phys, 1998, 108(21): 8 821-8 829. |
[8] | Mladenovic M. Rovibrational Hamiltonians for General Polyatomic Molecules in Spherical Polar Parametrization II: Nonorthogonal descriptions of internal molecular geometry[J]. J Chem Phys, 2000, 112(3): 1 082-1 095. |
[9] | Iung C, Gatti F, Viel A, et al. Vector Parametrization of the N-atom Problem in Quantum Mechanics with Non-orthogonal Coordinates[J]. Phys Chem Chem Phys, 1999, 1: 3 377-3 385. |
[10] | Eckart C. The Kinetic Energy of Polyatomic Molecules [J].Phys Rev, 1934, 46: 383-387. |
[11] | 马中骐. 量子三体问题[J]. 中国科学(A 辑), 2000, 30(8): 746-759. |
[12] | hrn Y, Linderberg J. Hyperspherical Co ordinates in Four Particle Systems[J]. Mol Phys, 1983, 49(1): 53-64. |
[13] | Costa L S, Soares Neto J J. A Wave Function Exp ansion for the Study of Tetra-atomic Molecules in Hyperspherical Coordinate Systems[J]. Mol Phys, 1999, 97(6): 725-730. |
[14] | Chapuisat X. Principal-axis Hyperspherical Descript ion of N-particle Systems: Quantum-mechanical treatment[J]. Phys Rev A, 1992, 45(7): 4 277-4 292. |
[15] | Edmonds A R. Angular Momentum in Quantum Mechanics [M]. Princeton: Princeton University Press, 1957. |
[16] | Gu X Y, Duan B, Ma Z Q. Conservation of Angular Momentum and Separation of Global Rotation in a Quantum N-body System[J].Phys Lett A, 2001, 281: 168-175. |
[17] | Gu X Y, Duan B, Ma Z Q. Independent Eigenstates of Angular Momentum in a Quantum N-body System[J]. Phys Rev A, 2001, 64(4):042108. |
[18] | Duan B, Gu X Y, Ma Z Q. Precise Calculation for Energy Levels of a Helium Atom in P States[J].Phys Lett A, 2001, 283: 229-236. |
[19] | Duan B, Gu X Y, Ma Z Q. Energy Levels in D Waves for a Helium Atom[J].Phys Rev A, 2001, 64(1): 012102. |
[20] | Duan B, Gu X Y, Ma Z Q. Energy Levels of a Positronium Negative Ion[J]. Chinese Phys Lett, 2001, 18(7): 854-856. |
[21] | Drake G W F. Atomic, Molelcular, and Optical Physics Handbook[M]. New York: Americal Insititute of Physics, 1996, 160. |
[22] | Drake G W F, Dalgarno A. 2p2 3P and 2p3p 1P States of the Helium Isoelectronic Sequence[J]. Phys Rev A, 1970, 1(5): 1 325-1 329. |
[23] | Quantum Three-body Problems[J]. Sci China, Ser A(in Chinese), 2000, 43(10): 1 093-1 107. |
上一张
下一张
上一张
下一张
计量
- 下载量()
- 访问量()
文章评分
- 您的评分:
-
10%
-
20%
-
30%
-
40%
-
50%