由CH4/Ar放电产生C2负离子,在超声射流条件下,观测到B←X(1-0)跃迁的激光诱导荧光激发谱.对该谱带的转动结构进行了标识,并得到X(v=0)和B(v=1)态的转动常数.另外测量了B(v=1)振动态的寿命,其寿命为80±1 ns.
参考文献
[1] | Honig R E.C2 anions observed in an MS/MS spectrum [J].J.Chem.Phys.,1954,22:1610. |
[2] | Herzberg G,Lagerqvist A.A new spectrum associated with diatomic carbon [J].Can.J.Phys.,1968,46:2363. |
[3] | Milligan D E,Jacox M E,Abouaf-Marguin L.Vacuum-ultraviolet photolysis of acetylene in inert matrices:spectrosc opic study of the species C2 [J].J.Chem.Phys.,1967,46:4562. |
[4] | Lineberger W C,Patterson T A.Two photon photodetachment spectroscopy:states [J].Chem.Phys.Lett.,1972,13:40. |
[5] | Jones P L,Mead R D,Lineberger W C.Photodetachment spectroscopy of autodetaching resonances [J].J.Chem.Phys.,1980,73:4419. |
[6] | Hefter U,Mead R D,Lineberger W C.Ultrahigh-resolution study of autodetachment in C-2 [J].Phys.Rev.A,1983,28:1429. |
[7] | Mead R D,Hefter U,Lineberger W C.Ultrahigh resolution spectroscopy of C-2:the A2∏μ state characterized by deperturbation methods [J].J.Chem.Phys.,1985,82:1723. |
[8] | Rehfuss B D,Liu D J,Crofton M W,et al.Infrared spectroscopy of carbo-ions.Ⅳ.the A2∏μ-X2∑g+ electronic transition of C-2 [J].J.Chem.Phys.,1988,89:129. |
[9] | Erwin K M,Lineberger W C.Photoelectron spectra of dicarbon(1-)and ethynyl(1-)[J].J.Phys.Chem.,1991,95:1167. |
[10] | Arnold D W,Bradforth S E,Neumark D M.Vibrationally resolved spectra of C.2-C11 by anion photoelectron spectroscopy [J].J.Chem.Phys.,1991,95:8753. |
[11] | Leutwyler S,Meyer J,Misev L.the lifetime of C-2 in rotational levels of B2∑+μ state in the gas phase [J].Chem.Phys.Lett.,1982,91:206. |
[12] | Weltner W,Van Zee R J.Carbon molecules,ions,and clusters [J].Chem.Rev.,1989,89:1713. |
[13] | Watts J D,Bartlett R J.J.Coupled-cluser calculation on the C2 molecules and C2+ and C2-molecular-ions [J].J.Chem.Phys.,1992,96:6073. |
[14] | Rosmus P,Werner H J.Multireference-CI calculations of radiative transition probabilities in C-2 [J].J.Chem.Phys.,1984,80:5085. |
[15] | Chen Y,Jin J,Hu C J,et al.Fluorescence excitation spectrum of a 2∏3/2-2∏3/2 transition of NiF [J].J.Mol.Spectrosc.,2000,203:37. |
[16] | Esther D B,Yuexing Z,Neumark D M.Stimulated raman pumping of C-2 probed via resonant two-photon detachment [J].Chem.Phys.Lett.,1995,244:400. |
[17] | Herzberg G.Spetra of Diatomic Molecules [M].Van Nostrand,Princeton,N J,1950. |
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